| CPC C23C 16/34 (2013.01) [C23C 16/45527 (2013.01); C23C 16/458 (2013.01)] | 15 Claims | 

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               1. A method of depositing a transition metal nitride-containing material on a substrate by a cyclic deposition process, the method comprising: 
            providing a substrate comprising a substrate surface in a reaction chamber, wherein the substrate surface comprises a material selected from the group consisting of bulk silicon, germanium, Group II-VI or Group III-V semiconductor materials, dielectric materials, tungsten, ruthenium, molybdenum, cobalt, aluminum, and copper; 
                providing an organometallic transition metal precursor to the reaction chamber in a vapor phase; 
                providing an auxiliary reactant to the reaction chamber in a vapor phase; and 
                providing a nitrogen precursor into the reaction chamber in a vapor phase to form a transition metal nitride on the substrate surface; 
                wherein the organometallic transition metal precursor comprises a transition metal from any of groups 4 to 6 of the periodic table of elements. 
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