US 12,404,462 B2
Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil
Michael Joseph Moore, Houston, TX (US); Bertrand Ray Klussmann, Houston, TX (US); and Carter James White, Houston, TX (US)
Assigned to Magēmā Technology LLC, Houston, TX (US)
Filed by Magēmā Technology LLC, Houston, TX (US)
Filed on May 26, 2021, as Appl. No. 17/331,396.
Application 17/331,396 is a continuation of application No. 16/719,485, filed on Dec. 18, 2019, granted, now 11,021,662.
Application 16/719,485 is a continuation of application No. 16/103,896, filed on Aug. 14, 2018, granted, now 10,836,966, issued on Nov. 17, 2020.
Application 16/103,896 is a continuation in part of application No. PCT/US2018/017855, filed on Feb. 12, 2018.
Application 16/103,896 is a continuation in part of application No. PCT/US2018/017863, filed on Feb. 12, 2018.
Claims priority of provisional application 62/589,479, filed on Nov. 21, 2017.
Claims priority of provisional application 62/458,002, filed on Feb. 12, 2017.
Prior Publication US 2021/0284919 A1, Sep. 16, 2021
This patent is subject to a terminal disclaimer.
Int. Cl. C10G 45/04 (2006.01); B01D 3/34 (2006.01); B01D 53/14 (2006.01); B01J 8/00 (2006.01); B01J 8/02 (2006.01); B01J 8/04 (2006.01); B01J 21/04 (2006.01); B01J 23/24 (2006.01); B01J 23/40 (2006.01); B01J 23/74 (2006.01); C10G 7/00 (2006.01); C10G 25/00 (2006.01); C10G 25/02 (2006.01); C10G 45/02 (2006.01); C10G 45/06 (2006.01); C10G 45/08 (2006.01); C10G 45/22 (2006.01); C10G 47/02 (2006.01); C10G 65/04 (2006.01); C10G 65/16 (2006.01); C10G 67/02 (2006.01); C10G 67/06 (2006.01); C10G 69/02 (2006.01); C10L 1/04 (2006.01); C10L 1/12 (2006.01); C10L 1/14 (2006.01); C10L 1/16 (2006.01)
CPC C10G 45/04 (2013.01) [B01D 3/343 (2013.01); B01D 53/1481 (2013.01); B01J 8/008 (2013.01); B01J 8/0278 (2013.01); B01J 8/0292 (2013.01); B01J 8/0457 (2013.01); B01J 8/0492 (2013.01); B01J 21/04 (2013.01); B01J 23/24 (2013.01); B01J 23/40 (2013.01); B01J 23/74 (2013.01); C10G 7/00 (2013.01); C10G 25/003 (2013.01); C10G 25/02 (2013.01); C10G 45/02 (2013.01); C10G 45/06 (2013.01); C10G 45/08 (2013.01); C10G 45/22 (2013.01); C10G 47/02 (2013.01); C10G 65/04 (2013.01); C10G 65/16 (2013.01); C10G 67/02 (2013.01); C10G 67/06 (2013.01); C10G 69/02 (2013.01); C10L 1/04 (2013.01); C10L 1/12 (2013.01); C10L 1/14 (2013.01); C10L 1/1608 (2013.01); B01J 2208/00557 (2013.01); B01J 2208/02 (2013.01); B01J 2208/025 (2013.01); C10G 2300/1037 (2013.01); C10G 2300/1044 (2013.01); C10G 2300/1048 (2013.01); C10G 2300/1059 (2013.01); C10G 2300/107 (2013.01); C10G 2300/1077 (2013.01); C10G 2300/201 (2013.01); C10G 2300/202 (2013.01); C10G 2300/205 (2013.01); C10G 2300/206 (2013.01); C10G 2300/207 (2013.01); C10G 2300/208 (2013.01); C10G 2300/30 (2013.01); C10G 2300/302 (2013.01); C10G 2300/308 (2013.01); C10G 2300/4012 (2013.01); C10G 2300/4018 (2013.01); C10G 2300/4062 (2013.01); C10G 2300/70 (2013.01); C10G 2300/80 (2013.01); C10G 2400/04 (2013.01); C10G 2400/06 (2013.01); C10L 2200/0263 (2013.01); C10L 2200/0438 (2013.01); C10L 2270/02 (2013.01); C10L 2270/026 (2013.01)] 13 Claims
OG exemplary drawing
 
1. A process for the production of a Product Heavy Marine Fuel Oil, the process comprising: mixing a quantity of Feedstock Heavy Marine Fuel Oil, wherein Feedstock Heavy Marine Fuel Oil complies with Table 2 of ISO 8217 (2017) as a residual marine fuel and has a sulfur content (ISO 14596 or ISO 8754) greater than 0.5% wt., with a quantity of Activating Gas mixture to give a Feedstock Mixture; contacting the Feedstock Mixture with one or more hydrotreating catalysts under reactive distillation conditions in a reaction vessel, wherein the reactive distillation conditions promote the formation of a Process Mixture from said Feedstock Mixture, wherein said one or more catalysts are in the form of a structured catalyst bed, and wherein a majority by weight of the Process Mixture is comprised of a Product Heavy Marine Fuel Oil component and a minority by weight of the Process Mixture is comprised of bulk gaseous component and by-product hydrocarbon component; and wherein the reactive distillation conditions promote separating the Product Heavy Marine Fuel Oil portion of the Process Mixture from the bulk gaseous components of the Process Mixture; and the by-product hydrocarbon components from the Product Heavy Marine Fuel Oil; and discharging the Product Heavy Marine Fuel Oil from the bottom of the reaction vessel.