US 11,744,077 B2
Vertical memory devices and methods of manufacturing the same
Sangmin Kang, Hwaseong-si (KR); Hanvit Yang, Suwon-si (KR); and Jihoon Choi, Suwon-si (KR)
Assigned to SAMSUNG ELECTRONICS CO., LTD., Suwon-si (KR)
Filed by SAMSUNG ELECTRONICS CO., LTD., Suwon-si (KR)
Filed on Feb. 10, 2021, as Appl. No. 17/173,179.
Claims priority of application No. 10-2020-0069614 (KR), filed on Jun. 9, 2020.
Prior Publication US 2021/0384200 A1, Dec. 9, 2021
Int. Cl. H10B 43/27 (2023.01); H10B 43/35 (2023.01)
CPC H10B 43/35 (2023.02) [H10B 43/27 (2023.02)] 20 Claims
OG exemplary drawing
 
1. A vertical memory device, comprising:
a channel on a substrate, the channel extending in a vertical direction substantially perpendicular to an upper surface of the substrate;
a charge storage structure on an outer sidewall of the channel, the charge storage structure including a tunnel insulation pattern, a charge storage pattern and a first blocking pattern sequentially stacked in a horizontal direction substantially parallel to the upper surface of the substrate; and
gate electrodes spaced apart from each other in the vertical direction on the substrate, each of the gate electrodes surrounding the charge storage structure,
wherein the first blocking pattern includes silicon oxide containing a halogen element, and
wherein a concentration of the halogen element included in the first blocking pattern gradually decreases from an outer sidewall facing a corresponding one of the gate electrodes toward an inner sidewall facing the charge storage pattern.