| CPC H01J 49/067 (2013.01) [G01N 30/7206 (2013.01); H01J 49/145 (2013.01); H01J 49/147 (2013.01)] | 17 Claims |

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1. A method of analyzing a sample with a mass spectrometer, the method comprising:
flowing the sample in a carrier gas comprising hydrogen through a sample entrance of the mass spectrometer;
ionizing the sample using an ion source of the mass spectrometer, the ion source comprising:
a plurality of components defining a flow path therethrough, an inner surface of at least one of the plurality of components having a coating of a layer of silicon, silicon hydride, or a combination thereof, the coating having a thickness between about 400 Angstroms to 1000 Angstroms; and
analyzing the ions based on ion mass.
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