US 12,391,889 B2
Recovery of aliphatic hydrocarbons
Jean-Paul Andre Marie Joseph Ghislain Lange, Amsterdam (NL); Kai Jürgen Fischer, Amsterdam (NL); Guus Van Rossum, Amsterdam (NL); Timothé Johannes Olthof, Amsterdam (NL); Sybe Sipma, Amsterdam (NL); Luis Alberto Grau Lisnier, Amsterdam (NL); and Hendrik Stichter, Amsterdam (NL)
Assigned to SHELL USA, INC., Houston, TX (US)
Appl. No. 18/247,103
Filed by SHELL OIL COMPANY
PCT Filed Oct. 12, 2021, PCT No. PCT/EP2021/078172
§ 371(c)(1), (2) Date Mar. 29, 2023,
PCT Pub. No. WO2022/079025, PCT Pub. Date Apr. 21, 2022.
Claims priority of application No. 20202268 (EP), filed on Oct. 16, 2020.
Prior Publication US 2023/0374400 A1, Nov. 23, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. C10G 53/06 (2006.01); C10G 1/00 (2006.01); C10G 55/04 (2006.01)
CPC C10G 53/06 (2013.01) [C10G 1/002 (2013.01); C10G 55/04 (2013.01); C10G 2300/202 (2013.01); C10G 2300/4081 (2013.01)] 12 Claims
OG exemplary drawing
 
1. A process for the recovery of aliphatic hydrocarbons from a liquid hydrocarbon feedstock stream comprising aliphatic hydrocarbons, heteroatom containing organic compounds and optionally aromatic hydrocarbons, wherein the liquid hydrocarbon feedstock stream comprises at least part of a hydrocarbon product formed in a process comprising cracking of waste plastics, said process comprising the steps of:
a) contacting at least part of the liquid hydrocarbon feedstock stream with an extraction solvent a) which contains one or more heteroatoms, and subjecting the liquid hydrocarbon feedstock stream to liquid-liquid extraction with the extraction solvent a), resulting in a first stream comprising aliphatic hydrocarbons and a second stream comprising extraction solvent a), aliphatic hydrocarbons, heteroatom containing organic compounds and optionally aromatic hydrocarbons;
b1) mixing at least part of the second stream resulting from step a) with a demixing solvent b) which contains one or more heteroatoms and has a miscibility in heptane which is lower than the miscibility of extraction solvent a) in heptane, and separating the resulting mixture into a first stream comprising aliphatic hydrocarbons and optionally aromatic hydrocarbons and a second stream comprising extraction solvent a), demixing solvent b), heteroatom containing organic compounds and optionally aromatic hydrocarbons;
b2) mixing at least part of the second stream resulting from step b1) with demixing solvent b) and separating the resulting mixture into a first stream comprising heteroatom containing organic compounds and optionally aromatic hydrocarbons and a second stream comprising extraction solvent a) and demixing solvent b);
wherein steps b1) and b2) are sub-steps of a step b) which comprises two or more sub-steps;
c) separating at least part of the second stream resulting from step b2) into a first stream comprising demixing solvent b) and a second stream comprising extraction solvent a);
d) recycling at least part of the extraction solvent a) from the second stream resulting from step c) to step a); and
e) optionally recycling at least part of the demixing solvent b) from the first stream resulting from step c) to one or more of the sub-steps of step b),
wherein:
(i) before step a), heteroatom containing organic compounds are removed from the liquid hydrocarbon feedstock stream by contacting at least part of that stream with a washing solvent d) which contains one or more heteroatoms and has a miscibility in heptane which is lower than the miscibility of extraction solvent a) in heptane.