US 12,391,817 B2
Functionalized carbon black, preparation thereof and use in vulcanizable rubber compositions
Hauke Westenberg, Cologne (DE); Conny Vogler, Ruppichteroth (DE); Werner Niedermeier, Bruehl (DE); Dirk Rechenbach, Eppstein (DE); and Arndt-Peter Schinkel, Marienhausen (DE)
Assigned to Orion Engineered Carbons IP GmbH & Co. KG, Monheim (DE)
Appl. No. 17/624,035
Filed by Orion Engineered Carbons IP GmbH & Co. KG, Monheim (DE)
PCT Filed Jun. 18, 2020, PCT No. PCT/EP2020/066887
§ 371(c)(1), (2) Date Dec. 30, 2021,
PCT Pub. No. WO2021/001156, PCT Pub. Date Jan. 7, 2021.
Claims priority of application No. 19183848 (EP), filed on Jul. 2, 2019.
Prior Publication US 2022/0363864 A1, Nov. 17, 2022
Int. Cl. C08K 3/04 (2006.01); B60C 1/00 (2006.01); C08F 212/08 (2006.01); C08F 236/06 (2006.01); C08K 3/22 (2006.01); C08K 5/19 (2006.01); C08K 5/372 (2006.01); C08K 9/04 (2006.01)
CPC C08K 3/04 (2013.01) [B60C 1/0016 (2013.01); B60C 1/0025 (2013.01); C08F 212/08 (2013.01); C08F 236/06 (2013.01); C08K 3/22 (2013.01); C08K 5/19 (2013.01); C08K 5/3725 (2013.01); C08K 9/04 (2013.01); C08K 2003/2206 (2013.01); C08K 2003/2217 (2013.01)] 19 Claims
 
1. A functionalized carbon black obtained by treating an oxidized carbon black with a sulfur-containing primary or secondary amine or a salt thereof,
wherein the sulfur-containing primary or secondary amine comprises a compound of the formula R1—Sx—Z—NR2R3 or Sx (—Z—NR2R3)2, wherein
Z is a divalent C1-C8 alkylene group,
x is an integer of at least 1, and
R1, R2 and R3 are each individually selected from hydrogen and a monovalent organic group comprising 1-20 carbon atoms.