| CPC B01L 7/525 (2013.01) [B01L 3/502792 (2013.01); B01L 2200/0647 (2013.01); B01L 2200/16 (2013.01); B01L 2300/0645 (2013.01); B01L 2300/161 (2013.01); B01L 2300/1805 (2013.01); B01L 2400/0427 (2013.01)] | 18 Claims |

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1. A method of thermal cycling a droplet comprising:
(a) providing a device comprising an array of electrodes wherein the array comprises first and second electrodes within a dielectric layer, and wherein:
(i) the first and second electrodes are separated by a gap, the gap comprising a space between the electrodes, the space being about 50 μM to about 200 μM, and the gap being a portion of the dielectric layer; and
(ii) the gap dielectric layer portion is configured to have a different thermal conductivity relative to the first and second electrodes;
(b) establishing a first temperature at the first electrode and a second temperature at the second electrode, and a thermal zone between the first electrode and the second electrode, the thermal zone comprising a temperature gradient;
(c) using one or more droplet operations mediated by the first and second electrodes to cycle a droplet between the first temperature and the second temperature.
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