| CPC A61C 7/08 (2013.01) [B32B 1/00 (2013.01); B32B 27/08 (2013.01); B32B 27/36 (2013.01); B32B 27/365 (2013.01); A61C 2201/00 (2013.01); B32B 2250/05 (2013.01); B32B 2250/244 (2013.01); B32B 2250/42 (2013.01); B32B 2270/00 (2013.01); B32B 2307/41 (2013.01); B32B 2307/558 (2013.01); B32B 2535/00 (2013.01)] | 20 Claims |

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1. A dental appliance for positioning a patient's teeth, comprising:
a polymeric shell comprising a plurality of cavities for receiving one or more teeth, wherein the polymeric shell comprises at least one arrangement of alternating polymeric layers ABA or BAB, wherein:
layer A comprises a thermoplastic polymer A, wherein the thermoplastic polymer A comprises polyethylene terephthalate glycol (PETg);
layer B comprises a thermoplastic polymer B, wherein the thermoplastic polymer B comprises polycyclohexylenedimethylene terephthalate glycol (PCTg);
each of the thermoplastic polymers A and B has a flexural modulus of about 1.0 GPa to about 4.0 GPa; and
each of the thermoplastic polymers A and B has a glass transition temperature (Tg) greater than about 40° C.,
wherein the polymeric shell includes an outer major surface and an inner major surface, wherein the outer major surface of the polymeric shell includes a set of performance enhancing layers, the set of performance enhancing layers including at least two performance enhancing layers selected from the group consisting of a tie layer, a thermoforming assistance layer, a moisture barrier layer, and a stain-resistant layer, and
wherein the set of performance enhancing layers includes at least one of: thermoplastic polyurethanes (TPU) or olefins.
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