| CPC H01J 49/4235 (2013.01) [H01J 49/065 (2013.01)] | 27 Claims |

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1. A mass spectrometry system comprising:
a first ion source and a second ion source that produce ions,
wherein the ions produced by the second ion source are calibration ions to calibrate the mass spectrometry system;
an ion transfer device that includes a plurality of electrodes, the plurality of electrodes are connected to one or more voltage sources, the one or more voltage sources supply one or more voltages to the plurality of electrodes of the ion transfer device,
wherein the ion transfer device receives the ions and forms a first ion packet and a second ion packet from the received ions,
wherein the ion transfer device receives the ions as a continuous stream of incoming ions during a first time period from an inlet of the ion transfer device, and forms the first ion packet by accumulating the continuous stream of the incoming ions during the first time period,
wherein, during a second time period when the ion transfer device delivers the first ion packet via an outlet of the ion transfer device, the ion transfer device receives the ions as the continuous stream of the incoming ions from the inlet of the ion transfer device to form the second ion packet by accumulating the continuous stream of the incoming ions, and
wherein the ion transfer device delivers the first ion packet and the second ion packet to the outlet of the ion transfer device as separate ion packets exiting the ion transfer device at a frequency in a range from 1 Hz to 1000 Hz; and
a mass analyzer that separates the ions in the first and the second ion packets based on mass-to-charge ratio of the ions,
wherein the ion transfer device periodically forms calibration ion packets from the calibration ions to calibrate the mass spectrometry system or the mass analyzer.
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