US 12,040,365 B1
Incorporating nitrogen in dipole engineering for multi-threshold voltage applications in stacked device structures
Pei Ying Lai, Hsinchu (TW); Cheng-Chieh Lin, Kaohsiung (TW); Hsueh-Ju Chen, Taipei (TW); Tsung-Da Lin, Hsinchu (TW); Cheng-Hao Hou, Hsinchu (TW); and Chi On Chui, Hsinchu (TW)
Assigned to TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD., Hsinchu (TW)
Filed by Taiwan Semiconductor Manufacturing Company, Ltd., Hsin-Chu (TW)
Filed on Dec. 21, 2023, as Appl. No. 18/392,150.
Application 18/392,150 is a continuation of application No. 18/521,569, filed on Nov. 28, 2023.
Claims priority of provisional application 63/486,542, filed on Feb. 23, 2023.
Int. Cl. H01L 29/40 (2006.01); H01L 21/02 (2006.01); H01L 21/283 (2006.01); H01L 21/3115 (2006.01); H01L 21/822 (2006.01); H01L 21/8234 (2006.01); H01L 21/8238 (2006.01); H01L 27/092 (2006.01); H01L 29/423 (2006.01); H01L 29/66 (2006.01)
CPC H01L 29/401 (2013.01) [H01L 21/02329 (2013.01); H01L 21/283 (2013.01); H01L 21/3115 (2013.01); H01L 21/8221 (2013.01); H01L 21/823462 (2013.01); H01L 21/823857 (2013.01); H01L 27/0922 (2013.01); H01L 29/42392 (2013.01); H01L 29/66439 (2013.01)] 20 Claims
OG exemplary drawing
 
1. A method comprising:
forming a first semiconductor layer stack having a first upper semiconductor layer over a first lower semiconductor layer and a second semiconductor layer stack having a second upper semiconductor layer over a second lower semiconductor layer;
forming high-k dielectric layers over the first upper semiconductor layer, the second upper semiconductor layer, the first lower semiconductor layer, and the second lower semiconductor layer, wherein the high-k dielectric layers have a same composition; and
performing a dipole engineering process to cause the high-k dielectric layers to have different compositions, wherein the dipole engineering process includes a nitrogen-containing thermal drive-in process and, after the dipole engineering process, at least two of the high-k dielectric layers have different dipole dopant concentrations and at least two of the high-k dielectric layers have different nitrogen concentrations.