| CPC B01J 23/745 (2013.01) [B01J 35/30 (2024.01); C01B 32/15 (2017.08); C01B 32/162 (2017.08); C01B 32/18 (2017.08); C01B 32/184 (2017.08); C01B 32/186 (2017.08); C01B 32/205 (2017.08); D01F 9/127 (2013.01); D01F 9/1272 (2013.01)] | 17 Claims |

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1. A process comprising:
pre-treating a naturally occurring polycrystalline iron oxide catalyst, wherein the pre-treatment comprises heating;
providing the pre-treated catalyst to a fluidized bed reactor;
in the fluidized bed rector, contacting at an elevated temperature, the pre-treated catalyst with a hydrocarbon gas to catalytically convert at least a portion of the hydrocarbon gas to hydrogen and carbon and thereby selectively synthesise carbon material; and
extracting from the fluidized bed reactor a first stream which includes the synthesised carbon material and a second stream comprising the hydrogen.
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