CPC H01M 4/525 (2013.01) [H01M 4/134 (2013.01); H01M 4/505 (2013.01); H01M 4/661 (2013.01); H01M 10/0525 (2013.01); H01M 10/0569 (2013.01); H01M 50/105 (2021.01); H01M 50/417 (2021.01); H01M 50/46 (2021.01); H01M 2004/021 (2013.01); H01M 2300/0028 (2013.01)] | 17 Claims |
1. An electrochemical cell comprising:
a cathode, the cathode comprising a polycrystalline cathode electrochemically active material comprising the formula Li1+xMO2+y, wherein −0.9≤x≤0.3, −0.3≤y≤0.3, and wherein M comprises Ni at 80 atomic percent or higher relative to total M, the cathode electrochemically active material comprising a non-uniform distribution of Co; and
an anode comprising an electrochemically active material and an anode current collector, the anode current collector comprising a metal other than copper, wherein said anode has an electrochemical redox potential of at least 400 mV versus Li/Li+,
wherein the electrochemical cell is characterized by unchanged performance for charge and discharge at rates from C/5 to 4C following 1000 cycles and subsequent storage for 33 months at 0 V condition.
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