US 12,030,859 B2
Polymerizable compound, polymerizable composition and optical film
Ji Ho Yun, Hwaseong-si (KR); Young Kuk Kim, Hwaseong-si (KR); Sung Il Yoon, Hwaseong-si (KR); Jun Yong Song, Hwaseong-si (KR); Seung Hyup Shin, Hwaseong-si (KR); and Jin Wuk Kim, Hwaseong-si (KR)
Assigned to DONGJIN SEMICHEM CO., LTD., Incheon (KR)
Filed by DONGJIN SEMICHEM Co., Ltd., Incheon (KR)
Filed on Dec. 4, 2020, as Appl. No. 17/111,931.
Claims priority of application No. 10-2019-0160046 (KR), filed on Dec. 4, 2019.
Prior Publication US 2021/0171478 A1, Jun. 10, 2021
Int. Cl. C07D 277/66 (2006.01); C07D 333/58 (2006.01); C08F 261/04 (2006.01); G02B 1/04 (2006.01); G02B 5/30 (2006.01)
CPC C07D 277/66 (2013.01) [C07D 333/58 (2013.01); C08F 261/04 (2013.01); G02B 1/04 (2013.01); G02B 5/3083 (2013.01)] 3 Claims
 
1. A compound
of Chemical Formula (1-6) below, wherein polymerizable groups are introduced both ends of the compound:

OG Complex Work Unit Chemistry
wherein, in Chemical Formula (1-6),
A1 and A2 each independently represent hydrogen, deuterium, a halogen, an amino group, a cyano group, a nitro group, a nitroso group, a sulfamoyl group, an isothiocyanate group, a thiocyanate group, a carboxyl group, a C1-C30 alkyl group, a C1-C30 alkylsulfinyl group, a C1-C30 alkylsulfonyl group, a C1-C30 alkylsulfanyl group, a C1-C12 fluoroalkyl group, a C2-C30 alkenyl group, a C1-C30 alkoxy group, a C1-C12 N-alkylamino group, a C2-C20 N,N-dialkylamino group, a C1-C6 N-alkylsulfamoyl group, a C2-C12 N,N-dialkylsulfamoyl group, a C3-C20 cycloalkyl group, or a C6-C50 aryl group,
D1 represents —S—,
D2 represents ═N—,
L1 is a direct bond or a C2-C10 alkynylene group having a triple bond, and
each R7 independently represents deuterium, a halogen, an amino group, a cyano group, a nitro group, a nitroso group, a sulfamoyl group, an isothiocyanate group, a thiocyanate group, a carboxyl group, a C1-C30 alkyl group, a C1-C30 alkylsulfinyl group, a C1-C30 alkylsulfonyl group, a C1-C30 alkylsulfanyl group, a C1-C12 fluoroalkyl group, a C2-C30 alkenyl group, a C1-C30 alkoxy group, a C1-C12 N-alkylamino group, a C2-C20 N,N-dialkylamino group, a C1-C6 N-alkylsulfamoyl group, a C2-C12 N,N-dialkylsulfamoyl group, a C3-C20 cycloalkyl group, or a C6-C50 aryl group, and
each m is independently an integer of 0 to 4,
each p is independently an integer of 0 to 10,
wherein E1 is represented by any one selected from the group consisting of Chemical Formulas Y-1, Y-5, Y-10 to Y-13 below:

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry
wherein, in Chemical Formulas Y-1, Y-5, Y-10 to Y-13,
Z3 of Chemical Formula Y-1 represents an isothiocyanate group or a thiocyanate group,
Z3 and R of Chemical Formula Y-2, Y5 and Y10 to Y13 each independently represent deuterium, a halogen, an amino group, a cyano group, a nitro group, a nitroso group, a sulfamoyl group, an isothiocyanate group, a thiocyanate group, a carboxyl group, a C1-C30 alkyl group, a C1-C30 alkylsulfinyl group, a C1-C30 alkylsulfonyl group, a C1-C30 alkylsulfanyl group, a C1-C12 fluoroalkyl group, a C2-C30 alkenyl group, a C1-C30 alkoxy group, a C1-C12 N-alkylamino group, a C2-C20 N,N-dialkylamino group, a C1-C6 N-alkylsulfamoyl group, a C2-C12 N,N-dialkylsulfamoyl group, a C3-C20 cycloalkyl group, or a C6-C50 aryl group, in which,
V1 and V2 each independently represent —S— or —O—,
W1 to W5 each independently represent —CR4═ or —N═, in which R4 independently represents hydrogen or a C1-C4 alkyl group.