US 11,697,642 B2
HMF preparation catalysed by anolyte fraction
Alireza Haji Begli, Ramsen (DE); Christine Kröner, Kindenheim (DE); Waldemar Tschilingiri, Worms (DE); Ralf Riemenschnitter, Carlsberg (DE); and Kay Mantyk, Obrigheim (DE)
Assigned to SÜDZUCKER AG, Mannheim (DE)
Appl. No. 17/58,560
Filed by SÜDZUCKER AG, Mannheim (DE)
PCT Filed May 28, 2019, PCT No. PCT/EP2019/063851
§ 371(c)(1), (2) Date Nov. 24, 2020,
PCT Pub. No. WO2019/229077, PCT Pub. Date Dec. 5, 2019.
Claims priority of application No. 102018208507.2 (DE), filed on May 29, 2018.
Prior Publication US 2021/0214327 A1, Jul. 15, 2021
Int. Cl. C07D 307/54 (2006.01); C07D 307/50 (2006.01)
CPC C07D 307/54 (2013.01) [C07D 307/50 (2013.01)] 26 Claims
 
1. A method for the production of 5-hydroxymethylfurfural (HMF) comprising the steps:
a) providing a fructose-containing component,
b) producing a catalytically active anolyte fraction by electrolysis of water,
c) mixing the fructose-containing component and the catalytically active anolyte fraction to obtain a reaction solution,
d) converting the fructose present in the reaction solution to HMF at a temperature of 90° C. to 200° C. to obtain a liquid HMF-containing product mixture, and
e) obtaining a liquid HMF-containing product mixture.