US 11,697,106 B2
Porous carbon material composites and their production process, adsorbents, cosmetics, purification agents, and composite photocatalyst materials
Hironori Iida, Kanagawa (JP); Seiichiro Tabata, Kanagawa (JP); Shinichiro Yamada, Kanagawa (JP); Tsutomu Noguchi, Kanagawa (JP); and Shun Yamanoi, Kanagawa (JP)
Assigned to SONY CORPORATION, Tokyo (JP)
Filed by Sony Corporation, Tokyo (JP)
Filed on Oct. 8, 2020, as Appl. No. 17/66,149.
Application 17/066,149 is a division of application No. 15/876,382, filed on Jan. 22, 2018, abandoned.
Application 15/140,569 is a division of application No. 12/741,967, abandoned, previously published as PCT/JP2009/066737, filed on Sep. 28, 2009.
Application 15/876,382 is a continuation of application No. 15/140,569, filed on Apr. 28, 2016, abandoned.
Claims priority of application No. 2008-250679 (JP), filed on Sep. 29, 2008; and application No. 2009-184350 (JP), filed on Aug. 7, 2009.
Prior Publication US 2021/0023535 A1, Jan. 28, 2021
Int. Cl. B01J 21/18 (2006.01); A61K 8/19 (2006.01); A61L 9/01 (2006.01); A61K 8/9711 (2017.01); A61K 8/9739 (2017.01); A61K 8/9794 (2017.01); A61K 47/06 (2006.01); A61Q 19/08 (2006.01); B01D 53/02 (2006.01); B01D 53/88 (2006.01); B01J 20/02 (2006.01); B01J 20/06 (2006.01); B01J 20/20 (2006.01); B01J 20/28 (2006.01); B01J 20/32 (2006.01); C02F 1/28 (2023.01); C01B 32/00 (2017.01); C01B 32/20 (2017.01); C01B 32/318 (2017.01); C25D 3/56 (2006.01); C25D 7/00 (2006.01); H01B 1/04 (2006.01); H01L 31/0264 (2006.01); A61L 9/20 (2006.01); B01J 35/00 (2006.01); C01B 32/30 (2017.01); A61K 8/9741 (2017.01); A61K 8/9789 (2017.01); B05D 1/18 (2006.01); B05D 3/04 (2006.01); B05D 3/10 (2006.01); H01F 1/01 (2006.01); B01J 21/06 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01); C02F 103/00 (2006.01)
CPC B01J 21/18 (2013.01) [A61K 8/19 (2013.01); A61K 8/9711 (2017.08); A61K 8/9739 (2017.08); A61K 8/9741 (2017.08); A61K 8/9789 (2017.08); A61K 8/9794 (2017.08); A61K 47/06 (2013.01); A61L 9/01 (2013.01); A61L 9/205 (2013.01); A61Q 19/08 (2013.01); B01D 53/02 (2013.01); B01D 53/885 (2013.01); B01J 20/02 (2013.01); B01J 20/0211 (2013.01); B01J 20/0229 (2013.01); B01J 20/0244 (2013.01); B01J 20/06 (2013.01); B01J 20/20 (2013.01); B01J 20/2803 (2013.01); B01J 20/28009 (2013.01); B01J 20/28011 (2013.01); B01J 20/28057 (2013.01); B01J 20/28069 (2013.01); B01J 20/28083 (2013.01); B01J 20/3204 (2013.01); B01J 20/3236 (2013.01); B01J 35/004 (2013.01); B05D 1/18 (2013.01); B05D 3/0473 (2013.01); B05D 3/0486 (2013.01); B05D 3/104 (2013.01); C01B 32/00 (2017.08); C01B 32/30 (2017.08); C01B 32/318 (2017.08); C02F 1/283 (2013.01); C02F 1/288 (2013.01); C25D 3/56 (2013.01); H01B 1/04 (2013.01); H01F 1/01 (2013.01); H01L 31/0264 (2013.01); A61K 2800/413 (2013.01); A61K 2800/522 (2013.01); A61K 2800/56 (2013.01); B01D 2253/102 (2013.01); B01D 2253/306 (2013.01); B01D 2253/311 (2013.01); B01D 2255/104 (2013.01); B01D 2255/106 (2013.01); B01D 2255/1021 (2013.01); B01D 2255/1023 (2013.01); B01D 2255/20761 (2013.01); B01D 2255/702 (2013.01); B01D 2255/802 (2013.01); B01D 2255/9205 (2013.01); B01D 2255/9207 (2013.01); B01J 21/063 (2013.01); B01J 35/1014 (2013.01); B01J 35/1038 (2013.01); B01J 37/0203 (2013.01); B01J 2220/485 (2013.01); C02F 2103/007 (2013.01); Y10T 428/249969 (2015.04)] 18 Claims
 
1. A process for producing a porous carbon material composite, the process comprising:
carbonizing a silicon-containing plant-derived material at from 800° C. to 1,400° C. and generating a precursor carbonized material with oxidized silicon compounds;
reducing the silicon in the precursor carbonized material by treating the carbonized material with a hydrofluoric acid or an alkali and removing the oxidized silicon compounds;
activating the precursor carbonized material after reducing the silicon in the precursor carbonized material by subjecting the precursor carbonized material to a steam stream and generating a porous carbon material; and
causing a functional material to adhere on the porous carbon material using a complexing treatment in which the porous carbon material is (a) immersed at 25° C. for 24 hours in a 0.5 mol/L aqueous solution of iron chloride, (b) then washed with water and, (c) then subjected to heat treatment at 750° C. for three hours in a nitrogen atmosphere to complete the creation of the porous carbon material composite.