US 12,351,778 B2
Laundry detergent formulation with biodegradable antiredeposition agent
Scott Backer, Phoenixville, PA (US); Randara Pulukkody, Lansdale, PA (US); John B. Case, Jr., Perkasie, PA (US); Saugata Nad, Brussels (BE); and Sangeeta Sanjeev Patel, Mumbai (IN)
Assigned to Dow Global Technologies LLC, Midland, MI (US); Rohm and Haas Company, Collegeville, PA (US); and Dow Silicones Corporation, Midland, MI (US)
Appl. No. 17/924,044
Filed by Dow Global Technologies LLC, Midland, MI (US); Dow Silicones Corporation, Midland, MI (US); and Rohm and Haas Company, Collegeville, PA (US)
PCT Filed Jun. 18, 2021, PCT No. PCT/US2021/037972
§ 371(c)(1), (2) Date Nov. 8, 2022,
PCT Pub. No. WO2021/262535, PCT Pub. Date Dec. 30, 2021.
Claims priority of application No. 202041026668 (IN), filed on Jun. 24, 2020.
Prior Publication US 2023/0174899 A1, Jun. 8, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. C11D 3/00 (2006.01); C11D 1/22 (2006.01); C11D 3/37 (2006.01)
CPC C11D 3/0036 (2013.01) [C11D 1/22 (2013.01); C11D 3/3757 (2013.01); C11D 2111/12 (2024.01)] 9 Claims
 
1. A laundry detergent formulation, comprising:
a detergent surfactant;
a builder;
a filler; and
an antiredeposition agent, wherein the antiredeposition agent is a polymer comprising:
(a) 10 to 65 wt % of structural units of formula I

OG Complex Work Unit Chemistry
wherein each R1 and R2 is independently selected from a hydrogen and a C1-3 alkyl group;
(b) 10 to 80 wt % of structural units of formula II

OG Complex Work Unit Chemistry
wherein each R3 is independently selected from a hydrogen and a —(O) CH3 group; and
(c) 10 to 65 wt % of structural units of formula III

OG Complex Work Unit Chemistry
wherein each R4 is independently selected from a hydrogen and a —CH3 group; and
wherein at least one of R1 and R2 is a C1-3 alkyl group in at least 1 mol % of the structural units of formula I in the antiredeposition agent; wherein the antiredeposition agent has a lactone end group and wherein the antiredeposition agent has a weight average molecular weight of 1,500 to 6,000 Daltons.