| CPC C04B 35/62222 (2013.01) [C04B 35/16 (2013.01); C04B 35/6261 (2013.01); C04B 35/62695 (2013.01); C23C 4/11 (2016.01); C04B 2235/3427 (2013.01); C04B 2235/3436 (2013.01); C04B 2235/5445 (2013.01); C04B 2235/9607 (2013.01); C04B 2235/9669 (2013.01)] | 16 Claims |

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1. An article comprising:
a substrate; and
a coating system on the substrate, wherein the coating system includes a thermal and/or environmental barrier coating (T/EBC) layer, wherein the T/EBC layer includes a silicate phase including a mixture of exactly five different rare earth metal cations.
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