US 12,346,021 B2
Simultaneous carbon nanotube growth, catalyst removal, boron nitride nanotube shell formation method for EUV pellicles
Pei-Cheng Hsu, Hsinchu (TW); Huan-Ling Lee, Hsinchu (TW); Hsin-Chang Lee, Hsinchu (TW); and Chin-Hsiang Lin, Hsinchu (TW)
Assigned to Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed by Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed on May 20, 2022, as Appl. No. 17/749,675.
Claims priority of provisional application 63/301,937, filed on Jan. 21, 2022.
Prior Publication US 2023/0236496 A1, Jul. 27, 2023
Int. Cl. G03F 1/62 (2012.01)
CPC G03F 1/62 (2013.01) 20 Claims
 
1. A method for forming a pellicle for an extreme ultraviolet lithography, comprising:
forming a pellicle membrane over a filter membrane, wherein forming the pellicle membrane comprises:
growing carbon nanotubes (CNTs) from in-situ formed metal catalyst particles in a first reaction zone of a reactor, each of the CNTs including a metal catalyst particle at a growing tip thereof;
growing boron nitride nanotubes (BNNTs) to surround individual CNTs in a second reaction zone of the reactor downstream of the first reaction zone, thereby forming heterostructure nanotubes each including a CNT core and a BNNT shell, wherein the metal catalyst particles are partially or completely removed during growing the BNNTs; and
collecting the heterostructure nanotubes on the filter membrane; and
transferring the pellicle membrane from the filter membrane to a membrane border.