US 12,344,802 B2
Process for partial upgrading of heavy oil
Howard Jemison, Houston, TX (US); David Staack, College Station, TX (US); and Kunpeng Wang, College Station, TX (US)
Assigned to THE TEXAS A&M UNIVERSITY SYSTEM, College Station, TX (US); and LTEOIL LLC, Houston, TX (US)
Filed by The Texas A&M University System, College Station, TX (US)
Filed on Jul. 15, 2024, as Appl. No. 18/772,602.
Application 18/335,782 is a division of application No. 17/048,637, granted, now 11,713,421, previously published as PCT/US2019/028338, filed on Apr. 19, 2019.
Application 18/772,602 is a continuation of application No. 18/335,782, filed on Jun. 15, 2023, granted, now 12,037,549.
Claims priority of provisional application 62/660,718, filed on Apr. 20, 2018.
Prior Publication US 2024/0368481 A1, Nov. 7, 2024
Int. Cl. C10G 15/12 (2006.01); B01D 3/14 (2006.01); C10G 55/04 (2006.01)
CPC C10G 15/12 (2013.01) [B01D 3/14 (2013.01); C10G 55/04 (2013.01); B01D 2257/60 (2013.01); C10G 2300/4081 (2013.01)] 20 Claims
OG exemplary drawing
 
1. A process for continuously upgrading heavy oil through plasma processing, using spark discharges in a plasma reactor, the process comprising:
passing, through a heavy oil feed, a heavy oil into a heat exchanger to bring the temperature of the heavy oil to first temperature;
forcing the heavy oil from the heat exchanger to an inter-electrode gap inside of the plasma reactor, wherein the inter-electrode gap is defined by a distance between a negative electrode and a positive electrode;
forcing a light hydrocarbon gas into the plasma reactor to mix with the heavy oil therein to form a first mixture in the inter-electrode gap, the first the first mixture comprising the heavy oil and the light hydrocarbon gas;
generating a spark-discharge in the inter-electrode gap to react the first mixture to generate a reacted first mixture;
flowing the reacted first mixture into a separator to separate a light hydrocarbon liquid and light hydrocarbon gas from the reacted first mixture;
adding fresh hydrogen and fresh hydrocarbon gas to the separated light hydrocarbon gas to produce a second mixture and recycling the second mixture to the plasma reactor to increase overall conversion of the heavy oil;
flowing heavy oil from the separator to the heat exchanger to combine with heavy oil from the heavy oil feed to produce combined heavy oil; and
obtaining upgraded oil by performing at least one of (1) removing the combined heavy oil, or (2) blending the combined heavy oil with the light hydrocarbon liquid.