US 12,012,643 B2
Method for the recovery of palladium
Angela Serpe, Cagliari (IT); Eros Perra, Cagliari (IT); and Americo Rigoldi, Cagliari (IT)
Assigned to UNIVERSITA' DEGLI STUDI DI CAGLIAR, Cagliari (IT)
Appl. No. 17/281,740
Filed by UNIVERSITA' DEGLI STUDI DI CAGLIAR, Cagliari (IT)
PCT Filed Oct. 2, 2019, PCT No. PCT/IB2019/058368
§ 371(c)(1), (2) Date Mar. 31, 2021,
PCT Pub. No. WO2020/070654, PCT Pub. Date Apr. 9, 2020.
Claims priority of application No. 102018000009093 (IT), filed on Oct. 2, 2018.
Prior Publication US 2021/0395858 A1, Dec. 23, 2021
Int. Cl. C22B 11/00 (2006.01); C22B 3/26 (2006.01)
CPC C22B 11/042 (2013.01) [C22B 3/302 (2021.05)] 20 Claims
 
1. A method for the recovery of palladium, comprising the steps of:
(A) providing a dispersion comprising:
an aqueous dispersing phase comprising palladium(II),
at least one non-ionic surfactant and
at least one compound bearing a beta-dithiocarbonyl group,
so as to form a hydrophobic complex of palladium(II) with the compound bearing a beta-dithiocarbonyl group;
(B) heating the dispersion resulting from step (A) to a temperature at least equal to its cloud point so as to obtain: a phase separation between the aqueous dispersing phase; and, a dispersed phase comprising a surfactant and at least a part of said hydrophobic complex;
(C) separating the dispersed phase from the aqueous dispersing phase resulting from step (B); and
(D) recovering the hydrophobic complex of palladium(II) with the compound bearing a beta-dithiocarbonyl group.