US 12,012,550 B2
Attenuated acid formulations for acid stimulation
Mohammed Sayed, Katy, TX (US); and Rajesh Kumar Saini, Cypress, TX (US)
Assigned to Saudi Arabian Oil Company, Dhahran (SA)
Filed by Saudi Arabian Oil Company, Dhahran (SA)
Filed on Dec. 13, 2021, as Appl. No. 17/548,752.
Prior Publication US 2023/0183560 A1, Jun. 15, 2023
Int. Cl. C09K 8/72 (2006.01); C09K 8/68 (2006.01); C09K 8/70 (2006.01)
CPC C09K 8/725 (2013.01) [C09K 8/685 (2013.01); C09K 8/703 (2013.01)] 15 Claims
OG exemplary drawing
 
1. A method for treating a carbonate reservoir with an attenuated acid formulation, comprising:
mixing an acidic compound with a hygroscopic chemical to form the attenuated acid formulation, wherein the acidic compound comprises a hydrochloric acid solution and the hydroscopic chemical comprises diethylene glycol, wherein the DEG comprises between 5 and 40 vol. % of the attenuated acid formulation; and
injecting the attenuated acid formulation into a carbonate formation, wherein the pore volume for breakthrough (PVBT) is less than 0.23 for an attenuated acid formulation comprising either a 28 wt. % or a 36 wt. % solution of HCl.