CPC C12Q 1/686 (2013.01) [C12Q 1/6818 (2013.01); G01N 21/66 (2013.01); C12Q 2565/301 (2013.01)] | 19 Claims |
1. A method for enriching or isolating a target-nucleic acid from a nucleic acid-containing sample, said method comprising:
a) receiving an electrolytic fluid solution including ions and a nucleic acid-containing sample in a fluid chamber having a first and second electrode, wherein at least one electrode has attached thereto a plurality of capture-probes or capture/primer probes complementary to the target-nucleic acid, wherein the capture probes are at the electrode-solution interface;
b) applying an annealing-voltage to the electrolytic fluid in proximity to the electrode-solution interface to generate an annealing-pH level by the interface, wherein the annealing-pH level causes annealing of any number of complementary base pairs between nucleic acid within the nucleic acid-containing sample and the capture-probes or capture/primer probes;
c) applying a denaturing-voltage to the electrolytic fluid in proximity to the electrode-solution interface to generate a denaturing-pH level by the interface, wherein the denaturing-pH level causes the denaturation of double-stranded nucleic acids, including hybridized pairs of capture probes or capture/primer probes and target-nucleic acids, that are either a particular number of base pairs shorter or a particular range of base pairs shorter than the full-length of a double-stranded capture-probe or capture/primer probe; and
d) modulating voltages between the annealing-voltage and denaturing-voltage, wherein multiple cycles of modulation are performed on the entire nucleic acid-containing sample while it is inside the fluid chamber, wherein after the final application of the corresponding pH level, the target-nucleic acid is enriched or isolated from the nucleic acid-containing sample by remaining bound to the capture-probes or capture/primer probes on the at least one electrode, wherein the modulating voltages between the annealing-voltage and denaturing-voltage is at a modulation frequency in the range of 0.1-1000 Khz.
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