| CPC H10B 41/27 (2023.02) [C23C 16/06 (2013.01); C23C 16/45525 (2013.01); C23C 16/50 (2013.01); H01L 21/28568 (2013.01); H01L 21/31116 (2013.01); H01L 21/67167 (2013.01); H01L 21/67207 (2013.01); H10D 30/6891 (2025.01); H10D 64/035 (2025.01)] | 7 Claims |

|
1. A memory structure comprising:
a plurality of alternating layers of a silicon material and a metal gate, the metal gate comprising a conformal barrier layer on the silicon material, a conformal α-tungsten (W) layer directly on the conformal barrier layer, and a bulk tungsten layer on the conformal α-tungsten (W) layer,
the conformal barrier layer comprising a metal nitride having a chemical formula of TiXN or TaXN, X being selected from one or more of aluminum (Al), silicon (Si), tungsten (W), lanthanum (La), yttrium (Yt), strontium (Sr), or magnesium (Mg), and
the conformal barrier layer having a thickness in a range of from 5 Å to 15 Å; and
a memory hole channel formed through the plurality of alternating layers of the silicon material and the metal, and the memory hole channel having a conformal layer of a poly-silicon material deposited directly on a first surface, a second surface, and a third surface of the memory hole channel.
|