US 11,999,679 B2
Chromium-catalyzed production of alcohols from hydrocarbons
Carlos A. Cruz, Kingwood, TX (US); Masud M. Monwar, Bartlesville, OK (US); Max P. McDaniel, Bartlesville, OK (US); Jared Barr, Bartlesville, OK (US); Kathy S. Clear, Bartlesville, OK (US); and William C. Ellis, Bartlesville, OK (US)
Assigned to Chevron Phillips Chemical Company LP, The Woodlands, TX (US)
Filed by Chevron Phillips Chemical Company LP, The Woodlands, TX (US)
Filed on Aug. 24, 2023, as Appl. No. 18/454,844.
Application 18/454,844 is a division of application No. 17/867,782, filed on Jul. 19, 2022, granted, now 11,753,358.
Application 17/867,782 is a division of application No. 17/501,020, filed on Oct. 14, 2021, granted, now 11,440,865, issued on Sep. 13, 2022.
Application 17/501,020 is a continuation of application No. 17/019,428, filed on Sep. 14, 2020, granted, now 11,180,435, issued on Nov. 23, 2021.
Claims priority of provisional application 62/900,687, filed on Sep. 16, 2019.
Prior Publication US 2023/0391700 A1, Dec. 7, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. C07C 29/72 (2006.01); B01J 21/06 (2006.01); B01J 21/08 (2006.01); B01J 23/26 (2006.01); B01J 37/08 (2006.01); B01J 37/34 (2006.01); B01J 38/02 (2006.01); C07C 29/09 (2006.01); C07C 29/48 (2006.01); C07C 29/50 (2006.01); C07C 31/20 (2006.01); C07C 37/08 (2006.01); C07C 37/58 (2006.01); C07C 45/33 (2006.01); C07C 51/215 (2006.01); B01J 35/40 (2024.01); B01J 35/61 (2024.01); B01J 35/63 (2024.01); C07C 29/17 (2006.01); C07C 31/04 (2006.01); C07C 45/29 (2006.01)
CPC C07C 29/72 (2013.01) [B01J 21/063 (2013.01); B01J 21/08 (2013.01); B01J 23/26 (2013.01); B01J 37/08 (2013.01); B01J 37/34 (2013.01); B01J 37/345 (2013.01); B01J 38/02 (2013.01); C07C 29/09 (2013.01); C07C 29/48 (2013.01); C07C 29/50 (2013.01); C07C 31/20 (2013.01); C07C 37/58 (2013.01); C07C 45/33 (2013.01); C07C 51/215 (2013.01); B01J 35/40 (2024.01); B01J 35/615 (2024.01); B01J 35/617 (2024.01); B01J 35/635 (2024.01); C07C 29/17 (2013.01); C07C 31/04 (2013.01); C07C 45/292 (2013.01)] 20 Claims
 
1. A supported catalyst comprising:
a chemically-treated solid oxide comprising sulfated alumina, fluorided alumina, fluorided silica-alumina, fluorided silica-coated alumina, or any combination thereof; and
a chromate compound in an amount from about 0.1 to about 25 wt. % of chromium, based on the weight of the catalyst.