US 12,319,646 B2
Low biuret urea production
Rahul Patil, Sittard (NL)
Assigned to STAMICARBON B.V., Sittard (NL)
Appl. No. 18/716,802
Filed by STAMICARBON B.V., Sittard (NL)
PCT Filed Feb. 21, 2023, PCT No. PCT/NL2023/050084
§ 371(c)(1), (2) Date Jun. 5, 2024,
PCT Pub. No. WO2023/158314, PCT Pub. Date Aug. 24, 2023.
Claims priority of application No. 22157781 (EP), filed on Feb. 21, 2022.
Prior Publication US 2024/0425449 A1, Dec. 26, 2024
Int. Cl. C07C 273/04 (2006.01)
CPC C07C 273/04 (2013.01) 20 Claims
OG exemplary drawing
 
1. A process for the production of urea from ammonia and carbon dioxide in a urea plant,
wherein the urea plant comprises a high pressure (HP) synthesis section comprising a reaction zone, a carbamate condenser and a stripper,
wherein the carbamate condenser comprises a shell-and-tube heat exchanger with a shell space and a first and a second horizontal tube bundle,
wherein the process comprises:
forming a urea synthesis solution comprising urea, water and ammonium carbamate in said reaction zone,
condensing gas from the stripper in the shell space thereby providing a carbamate-containing high pressure liquid stream;
expanding said urea synthesis solution from said synthesis section to medium pressure (MP) to give a first MP urea solution comprising carbamate;
heating said first MP urea solution in said first tube bundle, thereby decomposing said carbamate comprised in said first MP urea solution;
subjecting a fluid stream from the outlet of said first tube bundle to gas/liquid separation to give a second MP urea solution and an MP gas stream;
condensing said MP gas stream at medium pressure in a first condensation compartment thereby forming carbamate and heating through indirect heat exchanging contact a urea solution to be heated giving heated urea solution in a first evaporation stage; and
raising steam in said second tube bundle and using said steam to further heat through indirect heat exchanging contact said heated urea solution in a second evaporation stage.