CPC H01M 10/0569 (2013.01) [H01M 10/0525 (2013.01); H01M 10/0567 (2013.01); H01M 10/0568 (2013.01); H01M 2300/0028 (2013.01)] | 6 Claims |
1. An electrolyte solution comprising:
a compound (1) represented by the following formula (1); and
at least one compound (11) selected from the group consisting of compounds represented by the following formulas (11-1) to (11-4),
the formula (1) being:
![]() wherein M101 is P or P═O; R101 is a C1-C11 alkyloxy group, a silyloxy group, a C1-C11 alkylsilyloxy group, a C1-C11 alkoxysilyloxy group, or a C6-C18 arylsilyloxy group; n101 is a number of R101 s binding to M101 and is an oxidation number of M101 minus 1 or an oxidation number of M101 minus 3; when n101 is 2 or greater, R101 s are the same as or different from each other; and R102 to R104 are each individually a C1-C11 alkyl group, a C2-C11 alkenyl group, a C1-C11 alkyloxy group, or a C6-C11 aryl group,
the formula (11-1) being:
![]() wherein R111 and R112 are the same as or different from each other and are each a hydrogen atom, a fluorine atom, or an alkyl group optionally containing a fluorine atom; and R113 is an alkyl group free from a fluorine atom or an organic group containing an unsaturated carbon-carbon bond,
the formula (11-2) being:
![]() wherein R121 is an optionally fluorinated C1-C7 alkyl group, an optionally fluorinated C2-C8 alkenyl group, an optionally fluorinated C2-C9 alkynyl group, or an optionally fluorinated C6-C12 aryl group, and optionally contains at least one selected from the group consisting of O, Si, S, and N in a structure,
the formula (11-3) being:
![]() wherein R131 and R132 are (i) each individually H, F, an optionally fluorinated C1-C7 alkyl group, an optionally fluorinated C2-C7 alkenyl group, an optionally fluorinated C2-C9 alkynyl group, or an optionally fluorinated C5-C12 aryl group, or (ii) hydrocarbon groups binding to each other to form a 5-membered or 6-membered hetero ring with a nitrogen atom; and R131 and R132 each optionally contain at least one selected from the group consisting of O, S, and N in a structure, the formula (11-4) being:
![]() wherein Rf141 is CF3—, CF2H—, or CFH2—; and R141 is an optionally fluorinated C2-C5 alkenyl group or an optionally fluorinated C2-C8 alkynyl group and optionally contains Si in a structure.
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