CPC C08F 110/02 (2013.01) [C08F 4/02 (2013.01); C08F 4/65922 (2013.01); C08F 8/20 (2013.01); C08F 2420/00 (2013.01)] | 17 Claims |
1. A hybrid supported catalyst comprising:
one or more of a first transition metal compound represented by Chemical Formula 1;
one or more of a second transition metal compound represented by Chemical Formula 2; and
a support on which the first and second transition metal compounds are supported:
(Cp1R11)m(Cp2R12)M1(Z1)3-m [Chemical Formula 1]
in Chemical Formula 1,
M1 is a transition metal of Group 4;
Cp1 and Cp2 are the same as or different from each other, and each independently, any one selected from the group consisting of cyclopentadienyl, indenyl, 4,5,6,7-tetrahydro-1-indenyl, and fluorenyl radicals, which are unsubstituted or substituted with C1-20 hydrocarbon;
R11 and R12 are the same as or different from each other, and each independently, hydrogen, C1-20 alkyl, C1-20 alkoxy, C2-20 alkoxyalkyl, C6-20 aryl, C6-20 aryloxy, C2-20 alkenyl, C7-40 alkylaryl, C7-40 arylalkyl, C8-40 arylalkenyl, C2-20 alkynyl, or C2-20 heteroaryl comprising one or more heteroatoms of N, O, or S;
Z1 is halogen, C1-20 alkyl, C2-20 alkenyl, C7-40 alkylaryl, C7-40 arylalkyl, C6-20 aryl, an amino group, C2-20 alkylalkoxy, or C7-40 arylalkoxy; and
m is 1 or 0;
![]() in Chemical Formula 2,
A is carbon or silicon,
M2 is a transition metal of Group 4,
R21 is C6-20 aryl substituted with C1-20 alkyl,
R22 is C3-20 branched alkyl,
R23 to R25 are each independently C1-20 alkyl,
Z21 and Z22 are each independently halogen or C1-10 alkyl, and
n is an integer of 1 to 10.
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