US 11,993,665 B2
Hybrid supported catalyst and method of preparing polyolefin using the same
Sun Mi Kim, Daejeon (KR); Ue Ryung Seo, Daejeon (KR); Bog Ki Hong, Daejeon (KR); Eun Kyoung Song, Daejeon (KR); Daesik Hong, Daejeon (KR); Si Jung Lee, Daejeon (KR); Cheolhwan Jeong, Daejeon (KR); and Kiju Um, Daejeon (KR)
Assigned to LG Chem, Ltd., Seoul (KR)
Appl. No. 17/294,743
Filed by LG Chem, Ltd., Seoul (KR)
PCT Filed Sep. 25, 2020, PCT No. PCT/KR2020/013052
§ 371(c)(1), (2) Date May 18, 2021,
PCT Pub. No. WO2021/060908, PCT Pub. Date Apr. 1, 2021.
Claims priority of application No. 10-2019-0120102 (KR), filed on Sep. 27, 2019; application No. 10-2019-0120103 (KR), filed on Sep. 27, 2019; and application No. 10-2020-0124243 (KR), filed on Sep. 24, 2020.
Prior Publication US 2022/0017657 A1, Jan. 20, 2022
Int. Cl. C08F 110/02 (2006.01); C08F 4/02 (2006.01); C08F 4/6592 (2006.01); C08F 8/20 (2006.01)
CPC C08F 110/02 (2013.01) [C08F 4/02 (2013.01); C08F 4/65922 (2013.01); C08F 8/20 (2013.01); C08F 2420/00 (2013.01)] 17 Claims
 
1. A hybrid supported catalyst comprising:
one or more of a first transition metal compound represented by Chemical Formula 1;
one or more of a second transition metal compound represented by Chemical Formula 2; and
a support on which the first and second transition metal compounds are supported:
(Cp1R11)m(Cp2R12)M1(Z1)3-m  [Chemical Formula 1]
in Chemical Formula 1,
M1 is a transition metal of Group 4;
Cp1 and Cp2 are the same as or different from each other, and each independently, any one selected from the group consisting of cyclopentadienyl, indenyl, 4,5,6,7-tetrahydro-1-indenyl, and fluorenyl radicals, which are unsubstituted or substituted with C1-20 hydrocarbon;
R11 and R12 are the same as or different from each other, and each independently, hydrogen, C1-20 alkyl, C1-20 alkoxy, C2-20 alkoxyalkyl, C6-20 aryl, C6-20 aryloxy, C2-20 alkenyl, C7-40 alkylaryl, C7-40 arylalkyl, C8-40 arylalkenyl, C2-20 alkynyl, or C2-20 heteroaryl comprising one or more heteroatoms of N, O, or S;
Z1 is halogen, C1-20 alkyl, C2-20 alkenyl, C7-40 alkylaryl, C7-40 arylalkyl, C6-20 aryl, an amino group, C2-20 alkylalkoxy, or C7-40 arylalkoxy; and
m is 1 or 0;

OG Complex Work Unit Chemistry
in Chemical Formula 2,
A is carbon or silicon,
M2 is a transition metal of Group 4,
R21 is C6-20 aryl substituted with C1-20 alkyl,
R22 is C3-20 branched alkyl,
R23 to R25 are each independently C1-20 alkyl,
Z21 and Z22 are each independently halogen or C1-10 alkyl, and
n is an integer of 1 to 10.