US 11,986,810 B1
Selective reduction catalyst of α,β-unsaturated ketone using electronically weakly coupled 4,4′-divinylazoarylene-bridged diruthenium complex bearing two Ru(CO)(8-mercaptoquinolato(PiPr3)2 moieties
Obadah Subhi Abdel-Rahman, Al-Ahsa (SA)
Assigned to KING FAISAL UNIVERSITY, Al-Ahsa (SA)
Filed by KING FAISAL UNIVERSITY, Al-Ahsa (SA)
Filed on Jan. 5, 2024, as Appl. No. 18/405,177.
Int. Cl. B01J 31/24 (2006.01); B01J 31/20 (2006.01); B01J 31/22 (2006.01); B01J 37/02 (2006.01); B01J 37/03 (2006.01); B01J 37/04 (2006.01); B01J 37/06 (2006.01); C07F 15/00 (2006.01)
CPC B01J 31/2409 (2013.01) [B01J 31/20 (2013.01); B01J 31/226 (2013.01); B01J 31/2291 (2013.01); B01J 31/2295 (2013.01); B01J 37/0236 (2013.01); B01J 37/031 (2013.01); B01J 37/04 (2013.01); B01J 37/06 (2013.01); C07F 15/0046 (2013.01); B01J 2231/643 (2013.01); B01J 2531/0205 (2013.01); B01J 2531/821 (2013.01)] 13 Claims
 
1. A 4,4′-divinylazoarylene-bridged diruthenium complex with a general formula [{Ru(CO)(L-κ2[N,S]−)(PiPr3)2}2(μ—{CH═CH—C6H2—(iPr)2-2,6}2—N═N-4,4′)] having the formula I:

OG Complex Work Unit Chemistry