US 11,655,151 B2
Method for preparing a vanadium phosphate
Cyril Chomette, Aubervilliers (FR); Valérie Buissette, Aubervilliers (FR); Marc-David Braida, Aubervilliers (FR); and Thierry Le Mercier, Aubervilliers (FR)
Assigned to RHODIA OPERATIONS, Aubervilliers (FR)
Appl. No. 16/623,259
PCT Filed Jun. 14, 2018, PCT No. PCT/FR2018/051420
§ 371(c)(1), (2) Date Dec. 16, 2019,
PCT Pub. No. WO2018/229447, PCT Pub. Date Dec. 20, 2018.
Claims priority of application No. 1755505 (FR), filed on Jun. 16, 2017.
Prior Publication US 2021/0147236 A1, May 20, 2021
Int. Cl. C01B 25/37 (2006.01); C01B 25/45 (2006.01); C01B 25/455 (2006.01)
CPC C01B 25/372 (2013.01) [C01B 25/451 (2013.01); C01B 25/455 (2013.01); C01P 2002/72 (2013.01); C01P 2004/03 (2013.01); C01P 2004/61 (2013.01)] 18 Claims
OG exemplary drawing
1. A process for preparing a phosphate of formula (NH4)(VO2)(HPO4), the process consisting of stirring a mixture of V2O5 and of NH4H2PO4 in the solid state and adding water in an initial proportion of between 0.1% and 200.0%, this proportion being calculated relative to the whole of the two reactants V2O5 and NH4H2PO4, wherein V2O5 and NH4H2PO4 are powders that comprise particles having a diameter d50 of at most 100 μm, d50 being a median diameter obtained from a volume size distribution determined by a laser particle size analyzer.