US 11,654,426 B2
Method for manufacturing modified aluminosilicate, modified aluminosilicate, and method for manufacturing aromatic dihydroxy compound using the same
Yoshiya Matsukawa, Iwakuni (JP); Nobuhiko Horiuchi, Chiba (JP); Akihiro Okabe, Narashino (JP); Yoshihiro Kubota, Yokohama (JP); and Satoshi Inagaki, Yokohama (JP)
Assigned to MITSUI CHEMICALS, INC., Tokyo (JP)
Appl. No. 17/53,603
PCT Filed May 20, 2019, PCT No. PCT/JP2019/019939
§ 371(c)(1), (2) Date Nov. 6, 2020,
PCT Pub. No. WO2019/225549, PCT Pub. Date Nov. 28, 2019.
Claims priority of application No. JP2018-097032 (JP), filed on May 21, 2018; and application No. JP2018-097033 (JP), filed on May 21, 2018.
Prior Publication US 2021/0229085 A1, Jul. 29, 2021
Int. Cl. B01J 29/89 (2006.01); B01J 37/08 (2006.01); C01B 39/06 (2006.01); C01B 39/48 (2006.01); C07C 37/60 (2006.01); C07C 39/08 (2006.01)
CPC B01J 37/08 (2013.01) [B01J 29/89 (2013.01); C01B 39/06 (2013.01); C01B 39/48 (2013.01); C07C 37/60 (2013.01); C07C 39/08 (2013.01)] 12 Claims
1. A method for manufacturing a modified aluminosilicate, comprising:
a first step of treating an aluminosilicate with an acid;
a second step of primarily calcining the treated material obtained in the first step at 550° C. to 850° C.;
a third step of contacting the calcined material obtained in the second step with a liquid containing one or more elements selected from the group consisting of Group 4 elements and Group 5 elements on the periodic table in a temperature range of 20 to 150° C. to obtain a material; and
a fourth step of drying and secondarily calcining the material obtained in the third step,
wherein a specific surface area of the modified aluminosilicate is 50 to 1000 m2/g, and
the modified aluminosilicate is zeolite having an MSE framework.