US 12,305,148 B2
Siloxanes for treating textiles and for use in cleaning and care formulations
Frauke Henning, Essen (DE); Jörg Peggau, Essen (DE); Andrea Lohse, Bottrop (DE); Astrid Zündorff, Muelheim an der Ruhr (DE); Sarah Radloff, Bochum (DE); and Alexandra Trambitas, Alzenau (DE)
Assigned to Evonik Operations GmbH, Essen (DE)
Appl. No. 15/733,704
Filed by Evonik Operations GmbH, Essen (DE)
PCT Filed Mar. 26, 2019, PCT No. PCT/EP2019/057491
§ 371(c)(1), (2) Date Sep. 30, 2020,
PCT Pub. No. WO2019/192876, PCT Pub. Date Oct. 10, 2019.
Claims priority of application No. 18165408 (EP), filed on Apr. 3, 2018.
Prior Publication US 2021/0047591 A1, Feb. 18, 2021
Int. Cl. C11D 3/37 (2006.01); A61Q 19/10 (2006.01); C08G 77/26 (2006.01); C08K 5/17 (2006.01)
CPC C11D 3/3742 (2013.01) [A61Q 19/10 (2013.01); C08G 77/26 (2013.01); C08K 5/17 (2013.01)] 23 Claims
 
1. A siloxane (A) of formula (I):
M1a1M2a2M3a3M4a4D1b1D2b2D3b3T1c1T4c4Qd  Formula (I),
with
M1=[R13SiO1/2];
M2=[R2R12SiO1/2];
M3=[R3R12SiO1/2];
M4=[R4R12SiO1/2];
D1=[R12SiO2/2];
D2=[R1R2SiO2/2];
D3=[R1R3SiO2/2];
T1=[R1SiO3/2];
T4=[R4SiO3/2];
Q=[SiO4/2];
a1=0 to 32;
a2=0 to 32;
a3=0 to 32;
a4=0 to 6;
b1=1 to 1000;
b2=0 to 10;
b3=0 to 10;
c1=0 to 10;
c4=0 to 5;
d=0 to 10;
R1=each independently identical or different hydrocarbon radicals;
R2=R21-R22;
R21 each independently identical or different divalent hydrocarbon radicals having at least one hydroxyl group and optionally further oxygen atoms;
R22 each independently identical or different radicals of formula (II)

OG Complex Work Unit Chemistry
R3=R31-R32;
R31=R21;
R32=each independently identical or different radicals of formula (III)

OG Complex Work Unit Chemistry
R4=each independently identical or different alkoxy groups or acyloxy groups;
R7=—NH—;
R8=each independently identical or different radicals selected from the group consisting of methyl, ethyl n-propyl, isopropyl, n-butyl, isobutyl, and tert-butyl;
R9=each independently identical or different hydrogen and hydrocarbon radicals having 1 to 30 carbon atoms;
R11=each independently identical or different hydrocarbon radicals having at least one hydroxyl group and from 1 to 6 carbon atoms;
(A1)m-=each independently identical or different inorganic or organic anions with a charge of m−,
m 1 to 3; and
x=3;
wherein conditions (i) and (ii) are applicable:
a2+b2≥1; and  (i)
a3+b3≥1.  (ii)