US 12,305,127 B2
Recovery of aliphatic hydrocarbons
Jean-Paul Andre Marie Joseph Ghislain Lange, Amsterdam (NL); Guus Van Rossum, Amsterdam (NL); Timothé Johannes Olthof, Amsterdam (NL); Kai Jürgen Fischer, Amsterdam (NL); Hendrik Stichter, Amsterdam (NL); Jose Atilio Quevedo Enriquez, Amsterdam (NL); and Luis Alberto Grau Lisnier, Amsterdam (NL)
Assigned to SHELL USA, INC., Houston, TX (US)
Appl. No. 18/248,904
Filed by SHELL OIL COMPANY, Houston, TX (US)
PCT Filed Nov. 12, 2021, PCT No. PCT/EP2021/081486
§ 371(c)(1), (2) Date Apr. 13, 2023,
PCT Pub. No. WO2022/101392, PCT Pub. Date May 19, 2022.
Claims priority of application No. 20207461 (EP), filed on Nov. 13, 2020.
Prior Publication US 2023/0392088 A1, Dec. 7, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. C10G 53/08 (2006.01); C10G 1/00 (2006.01); C10G 1/10 (2006.01); C10G 55/04 (2006.01)
CPC C10G 53/08 (2013.01) [C10G 1/002 (2013.01); C10G 1/10 (2013.01); C10G 55/04 (2013.01); C10G 2300/202 (2013.01)] 10 Claims
OG exemplary drawing
 
1. A process for the recovery of aliphatic hydrocarbons from a liquid hydrocarbon feedstock stream from waste plastics comprising aliphatic hydrocarbons, heteroatom containing organic compounds and optionally aromatic hydrocarbons, said process comprising the steps of:
a) mixing at least part of the liquid hydrocarbon feedstock stream with a washing solvent a) which contains one or more heteroatoms and separating the resulting mixture into a first stream comprising washing solvent a) and heteroatom containing compounds and a second stream comprising aliphatic hydrocarbons, heteroatom containing organic compounds and optionally aromatic hydrocarbons; and
b) contacting at least part of the second stream resulting from step a) with an extraction solvent b) which contains one or more heteroatoms and subjecting that stream to liquid-liquid extraction with extraction solvent b), resulting in a first stream comprising aliphatic hydrocarbons and optionally heteroatom containing organic compounds and a second stream comprising extraction solvent b), heteroatom containing organic compounds and optionally aromatic hydrocarbons;
wherein:
(i) during step a), at least part of the liquid hydrocarbon feedstock stream is contacted with a sorption agent before the first and second streams are separated in step a); and
(ii) between a step preceding step a) and the step a), at least part of a second stream resulting from the step preceding step a) is contacted with a sorption agent; and
(iii) between steps a) and b), at least part of the second stream resulting from step a) is contacted with a sorption agent; and
(iv) the first stream resulting from step b) comprises aliphatic hydrocarbons and heteroatom containing organic compounds and, after step b), at least part of that stream is contacted with a sorption agent.