	US 12,304,923 B2
	Use of ionization radiation source in preparation of porous crystalline material
Shuao Wang, Suzhou (CN); Mingxing Zhang, Suzhou (CN); and Junchang Chen, Suzhou (CN)
Assigned to SOOCHOW UNIVERSITY, Suzhou (CN)
Appl. No. 17/424,870
Filed by SOOCHOW UNIVERSITY, Suzhou (CN)
PCT Filed Apr. 27, 2020, PCT No. PCT/CN2020/087265 § 371(c)(1), (2) Date Jul. 21, 2021, PCT Pub. No. WO2021/212532, PCT Pub. Date Oct. 28, 2021.
Claims priority of application No. 202010333538.X (CN), filed on Apr. 24, 2020.
Prior Publication US 2022/0315610 A1, Oct. 6, 2022
Int. Cl. C07D 251/24 (2006.01); C07F 7/00 (2006.01)

CPC C07F 7/003 (2013.01) [C07D 251/24 (2013.01)]

19 Claims

1. A method for synthesizing a porous crystalline material, comprising:

irradiating a reaction mixture comprising a metal precursor and an organic ligand with an ionization radiation source at a temperature between 20° C. and 30° C. and normal pressure, wherein the ionization radiation source provides the energy required to synthesize a metal-organic framework (MOFs) or covalent-organic framework (COFs) material.