US 11,984,595 B2
Lithium secondary battery
Kyung Bin Yoo, Daejeon (KR); Kook Hyun Han, Daejeon (KR); and Duck Chul Hwang, Daejeon (KR)
Assigned to SK ON CO., LTD., Seoul (KR)
Filed by SK INNOVATION CO., LTD., Seoul (KR)
Filed on Oct. 12, 2021, as Appl. No. 17/499,071.
Application 17/499,071 is a continuation of application No. 16/250,732, filed on Jan. 17, 2019, granted, now 11,211,605.
Claims priority of application No. 10-2018-0006188 (KR), filed on Jan. 17, 2018.
Prior Publication US 2022/0029163 A1, Jan. 27, 2022
Int. Cl. H01M 4/525 (2010.01); H01M 4/02 (2006.01); H01M 4/505 (2010.01); H01M 10/0525 (2010.01); H01M 10/0585 (2010.01)
CPC H01M 4/525 (2013.01) [H01M 4/505 (2013.01); H01M 10/0525 (2013.01); H01M 10/0585 (2013.01); H01M 2004/021 (2013.01); H01M 2004/028 (2013.01)] 6 Claims
OG exemplary drawing
 
1. A cathode active material for a lithium secondary battery, comprising:
a lithium metal oxide particle having a form of secondary particle in which a plurality of primary particles are aggregated,
wherein the primary particles include a particle having a rod-type shape, and
wherein the lithium metal oxide particle is represented by Chemical Formula 1;
LixM1aM2bM3cOy  [Chemical Formula 1]
wherein in Chemical Formula, M1, M2 and M3 represents a first metal, a second metal and a third metal, respectively, and the first metal is Ni, the second metal is Mn and the third metal is Co,
0<x≤1.1, 2≤y≤2.02, 0.8≤a≤0.9, 0.01≤b≤0.2, 0.04≤c≤0.2, 0.091≤c/(a+c)≤0.111, and a+b+c=1,
wherein the first metal includes a decreasing concentration gradient region only at a specific portion between a central portion of the lithium metal oxide particle and a surface of the lithium metal oxide particle, and the third metal has a constant concentration from the central portion of the lithium metal oxide particle to the surface of the lithium metal oxide particle,
wherein a molar ratio of the first metal at the surface is 0.770 or more based on a total amount of the first metal, the second metal and the third metal,
wherein the first metal and the second metal do not have a continuous concentration gradient in a region of 0.4 μm radius from a center of the lithium metal oxide particle.