US 11,981,832 B2
Curable film-forming compositions comprising catalyst associated with a carrier and methods for coating a substrate
Scott J. Moravek, Mars, PA (US); and Davina J. Schwartzmiller, Rural Valley, PA (US)
Assigned to PPG Industries Ohio, Inc., Cleveland, OH (US)
Filed by PPG INDUSTRIES OHIO, INC., Cleveland, OH (US)
Filed on Dec. 12, 2022, as Appl. No. 18/064,309.
Application 16/908,190 is a division of application No. 14/075,288, filed on Nov. 8, 2013, abandoned.
Application 18/064,309 is a continuation of application No. 16/908,190, filed on Jun. 22, 2020, granted, now 11,555,127.
Prior Publication US 2023/0125819 A1, Apr. 27, 2023
Int. Cl. C09D 189/00 (2006.01); B05D 1/02 (2006.01); C08G 18/24 (2006.01); C08J 3/24 (2006.01); C08K 9/10 (2006.01); C09D 5/02 (2006.01); C09D 7/40 (2018.01); C09D 7/62 (2018.01); C09D 7/65 (2018.01); C09D 175/02 (2006.01); C09D 175/04 (2006.01); C09D 175/14 (2006.01); B05D 1/36 (2006.01); B05D 3/12 (2006.01)
CPC C09D 7/70 (2018.01) [B05D 1/02 (2013.01); C08G 18/246 (2013.01); C08J 3/241 (2013.01); C08K 9/10 (2013.01); C09D 5/024 (2013.01); C09D 7/62 (2018.01); C09D 7/65 (2018.01); C09D 175/02 (2013.01); C09D 175/04 (2013.01); C09D 175/14 (2013.01); C09D 189/00 (2013.01); B05D 1/36 (2013.01); B05D 3/12 (2013.01); C08J 2361/24 (2013.01); Y10T 428/31768 (2015.04); Y10T 428/31942 (2015.04)] 20 Claims
 
1. A coated article prepared by applying a sprayable coating composition to at least a portion of a substrate, wherein the coating composition comprises:
a) a curable waterborne or solventborne film-forming resin; and
b) a catalyst coated on, hydrogen bonded with, contained within or encapsulated by a carrier, said carrier comprising gelatin, polyoxymethylene urea formaldehyde, melamine formaldehyde, or silica;
wherein said applying is conducted to impart shear force to the carrier, which thereby releases the catalyst from the carrier, and upon application of the shear force, at least some of the catalyst is released from the carrier, and wherein the carrier is not formed from the film-forming resin (a).