US 11,981,759 B2
Photocurable composition
Fen Wan, Austin, TX (US); Weijun Liu, Cedar Park, TX (US); and Timothy Brian Stachowiak, Austin, TX (US)
Assigned to CANON KABUSHIKI KAISHA, Tokyo (JP)
Filed by CANON KABUSHIKI KAISHA, Tokyo (JP)
Filed on May 18, 2022, as Appl. No. 17/664,037.
Prior Publication US 2023/0374167 A1, Nov. 23, 2023
Int. Cl. C08F 2/46 (2006.01); C08F 2/50 (2006.01); C08F 212/36 (2006.01); C08F 222/10 (2006.01); C08G 61/04 (2006.01); C08K 5/13 (2006.01); C08K 5/3417 (2006.01)
CPC C08F 2/50 (2013.01) [C08F 212/36 (2013.01); C08F 222/102 (2020.02); C08K 5/13 (2013.01); C08K 5/3417 (2013.01)] 19 Claims
 
19. A method of manufacturing an article, comprising:
applying a layer of a photocurable composition on the substrate, wherein the photocurable composition comprises a polymerizable material and at least one photoinitiator, the polymerizable material comprising at least one multi-functional vinylbenzene monomer in an amount of at least 30 wt % based on the total weight of the polymerizable material, the at least one photoinitiator including an oxime ester compound, and amount of the polymerizable material is at least 85 wt % based on the total weight of the photocurable composition;
bringing the photocurable composition into contact with a template or a superstrate;
irradiating the photocurable composition with light to form a photo-cured layer;
removing the template or the superstrate from the photo-cured layer;
forming a pattern on the substrate;
processing the substrate on which the pattern has been formed in the forming; and
manufacturing an article from the substrate processed in the processing.