US 11,980,865 B2
Contaminant removal by zero-valent iron-based green sorption media
Ni-Bin Chang, Orlando, FL (US); Debra Reinhart, Orlando, FL (US); and A H M Anwar Sadmani, Orlando, FL (US)
Assigned to University of Central Florida Research Foundation, Inc., Orlando, FL (US)
Filed by University of Central Florida Research Foundation, Inc., Orlando, FL (US)
Filed on Nov. 28, 2023, as Appl. No. 18/521,289.
Application 18/521,289 is a division of application No. 18/159,769, filed on Jan. 26, 2023, granted, now 11,896,948.
Claims priority of provisional application 63/267,406, filed on Feb. 1, 2022.
Prior Publication US 2024/0091738 A1, Mar. 21, 2024
Int. Cl. B01J 20/12 (2006.01); B01J 20/02 (2006.01); B01J 20/10 (2006.01); C02F 1/28 (2023.01); C02F 101/10 (2006.01); C02F 101/16 (2006.01); C02F 101/36 (2006.01)
CPC B01J 20/0229 (2013.01) [B01J 20/103 (2013.01); B01J 20/12 (2013.01); C02F 1/288 (2013.01); C02F 1/281 (2013.01); C02F 2101/105 (2013.01); C02F 2101/16 (2013.01); C02F 2101/36 (2013.01); C02F 2101/40 (2013.01)] 6 Claims
OG exemplary drawing
 
1. A composition for treating water containing one or more per- or polyfluoroalkyl substances, the composition comprising:
at most 5% (v/v) zero-valent iron particles, approximately 4% (v/v) clay particles, and approximately 91% (v/v) sand particles,
wherein, during flowing an amount of water through a fixed bed filter including the composition, the zero-valent iron particles are configured to oxidize the one or more per- or polyfluoroalkyl substances via a chemical oxidation reaction to generate at least one fluorinated carbon group and an oxidation-reaction-induced byproduct, the oxidation-reaction-induced byproduct including a portion of the one or more per- or polyfluoroalkyl substances, such that the oxidation-reaction-induced byproduct has a length smaller than a length of each of the one or more per- or polyfluoroalkyl substances, thereby promoting adsorption of the oxidation-reaction-induced byproduct by hydrophilic films surrounding the zero-valent iron particles, and thereby removing an amount of the one or more per- or polyfluoroalkyl substances from the water, and
wherein, during flowing the amount of water through the fixed bed filter including the composition, the zero-valent iron particles and the clay particles are configured to promote adsorption of the one or more per- or polyfluoroalkyl substances, thereby removing an amount of the one or more per- or polyfluoroalkyl substances.