| CPC H10K 50/121 (2023.02) [H10K 85/311 (2023.02); H10K 85/6572 (2023.02); H10K 2101/25 (2023.02); H10K 2101/30 (2023.02); H10K 2101/90 (2023.02); H10K 2102/351 (2023.02)] | 20 Claims |

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1. An organic electroluminescent device, comprising an anode, a cathode, an emitting layer arranged between the anode and the cathode, and an assistant luminescent layer located on one side, facing the anode, of the emitting layer, wherein
the assistant luminescent layer comprises a first host material and a first fluorescent guest material;
the emitting layer comprises a second host material, a TADF material, and a second fluorescent guest material; and
the first host material and the first fluorescent guest material satisfy:
S1(B)−T1(B)>0.2 eV;
S1(B)>S1(C);
T1(B)>T1(C);
∥HOMO(B)−LUMO(C)|−S1(C)|≤0.2 eV, wherein
the lowest singlet state energy of the first host material is S1(B), and the lowest triplet state energy is T1(B);
the lowest singlet state energy of the first fluorescent guest material is S1(C), and the lowest triplet state energy is T1(C); and
the highest occupied molecular orbital energy level of the first host material is HOMO (B); and the lowest occupied molecular orbital energy level of the first fluorescent guest material is LUMO (C).
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