| CPC H01L 23/53238 (2013.01) [H01L 21/76807 (2013.01); H01L 21/76834 (2013.01); H01L 21/76837 (2013.01); H01L 23/5283 (2013.01); H10B 12/01 (2023.02)] | 14 Claims |

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1. A method of forming a semiconductor structure, comprising:
providing a substrate, a dielectric layer on the substrate, the dielectric layer having a trench;
forming a metallic copper layer filling the trench;
forming a contact layer on an upper surface of the metallic copper layer, a material of the contact layer containing cuprous ions; and
forming a barrier layer on an upper surface of the contact layer, a material of the barrier layer containing a same element as the material of the contact layer;
wherein the material of the contact layer is cuprous thiocyanate, and the material of the barrier layer is silicon carbon nitride.
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