US 12,291,646 B2
Photocurable (meth)acrylate compositions
Shuhua Jin, Cheshire, CT (US); and Chih-Min Cheng, Westford, MA (US)
Assigned to Henkel AG & Co. KGAA, Duesseldorf (DE)
Filed by Henkel AG & Co. KGaA, Duesseldorf (DE)
Filed on Mar. 14, 2022, as Appl. No. 17/654,613.
Application 17/654,613 is a continuation of application No. PCT/US2020/051644, filed on Sep. 18, 2020.
Claims priority of provisional application 62/902,659, filed on Sep. 19, 2019.
Prior Publication US 2022/0204809 A1, Jun. 30, 2022
Int. Cl. C09D 175/14 (2006.01); B01D 67/00 (2006.01); B01D 69/02 (2006.01); B01D 69/12 (2006.01); B01D 71/52 (2006.01); B01D 71/54 (2006.01); C09D 7/43 (2018.01); C09D 7/65 (2018.01); B01D 61/02 (2006.01)
CPC C09D 175/14 (2013.01) [B01D 67/0088 (2013.01); B01D 69/02 (2013.01); B01D 69/12 (2013.01); B01D 71/5211 (2022.08); B01D 71/54 (2013.01); C09D 7/43 (2018.01); C09D 7/65 (2018.01); B01D 61/025 (2013.01); B01D 2325/30 (2013.01)] 26 Claims
 
1. A photocurable composition comprising:
a) a (meth)acrylate-functionalized polyether urethane component, wherein the (meth)acrylate-functionalized polyether urethane component is present in an amount of about 20% to about 60% by weight based on the total weight of the curable composition;
b) a (meth)acrylate monomer;
c) an organic filler; and
d) a photoinitiator,
wherein when exposed to UV or visible light the curable composition forms a cured reaction product, the cured reaction product demonstrates a loss of mass of: 1) less than 2% when exposed to acidic, aqueous conditions of a pH=1.5 for about 4 weeks at a temperature of about 50° C. and/or 2) less than 3% when exposed to basic, aqueous conditions of a pH=12.5 for about 4 weeks at a temperature of about 50° C.