| CPC H10K 85/654 (2023.02) [C07D 401/10 (2013.01); C07D 401/14 (2013.01); C07D 413/14 (2013.01); C07D 417/14 (2013.01); H10K 85/40 (2023.02); H10K 85/631 (2023.02); H10K 50/11 (2023.02); H10K 50/18 (2023.02)] | 8 Claims |
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1. An organic electroluminescence device, comprising:
a first electrode;
a hole transport region on the first electrode, the hole transport region including:
a hole injection layer on the first electrode;
a hole transport layer on the hole injection layer; and
an electron blocking layer on the hole transport layer;
an emission layer on the hole transport region;
an electron transport region on the emission layer; and
a second electrode on the electron transport region,
wherein the first electrode and the second electrode each independently comprise at least one selected from Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF/Ca, LiF/Al, Mo, Ti, In, Sn, and Zn, a compound of two or more thereof, a mixture of two or more thereof, and an oxide thereof,
wherein the emission layer includes a second heterocyclic compound represented by Formula 4 as a dopant, and
the electron blocking layer includes a first heterocyclic compound represented by the following Formula 2-1, and does not include the second heterocyclic compound:
 wherein, in Formula 2-1,
L1 is a substituted phenylene group, a substituted divalent biphenyl group, or a substituted or unsubstituted fluorenylene group, and L2 is a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, wherein the substituents of L1 and L2 are each independently selected from the group consisting of a deuterium atom, a halogen atom, a nitro group, an amino group, a silyl group, a boron group, a phosphine oxide group, a phosphine sulfide group, an alkyl group, an alkenyl group, an aryl group, and a heterocycle, provided that the substituent of L1 does not form a ring with an adjacent group, and the substituent of L2 does not form a ring with an adjacent group,
“n” is 0 or 1,
R1-1, R1-2, R2-1, and R2-2 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms,
R1-1, R1-2, R2-1, and R2-2 are separate or combined with an adjacent group to form a ring,
“c” to “f” are each independently an integer of 0 to 4,
X3 and X4 are each independently Si,
R3 to R6 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms, and “g” to “j” are each independently an integer of 0 to 5,
 and
wherein, in Formula 4,
Z1 is —CO—, or —SO2—,
R8 is a hydrogen atom, a deuterium atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 ring carbon atoms,
a thiophenyl group, a furanyl group, a pyrrolyl group, an indolyl group, a carbazolyl group, an N-arylcarbazolyl group, an N-heteroaryl carbazolyl group, an N-alkyl carbazolyl group, a benzocarbazole group, a benzothiophenyl group, a benzofuranyl group, a thienothiophene group, a phenoxazinyl group, a phenothiazinyl group, a dibenzosilole group, a dibenzothiophenyl group, or a dibenzofuranyl group, each being unsubstituted or substituted with at least one substituent selected from the group consisting of a deuterium atom, an amino group, a silyl group, a boron group, an alkyl group, an alkenyl group, or an aryl group;
R9 is a deuterium atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 ring carbon atoms,
a thiophenyl group, a furanyl group, a pyrrolyl group, an indolyl group, a carbazolyl group, an N-arylcarbazolyl group, an N-heteroaryl carbazolyl group, an N-alkyl carbazolyl group, a benzocarbazole group, a benzothiophenyl group, a benzofuranyl group, a thienothiophene group, a phenoxazinyl group, a phenothiazinyl group, a dibenzosilole group, a dibenzothiophenyl group, or a dibenzofuranyl group, each being unsubstituted or substituted with at least one substituent selected from the group consisting of a deuterium atom, an amino group, a silyl group, a boron group, an alkyl group, an alkenyl group, or an aryl group;
“q” and “r” are each independently an integer of 1 to 4,
Y1 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 2 to 20 carbon atoms, a substituted or unsubstituted naphthyl, fluorenyl, anthracenyl, phenanthryl, quaterphenyl, quinquephenyl, sexiphenyl, biphenylene, triphenylene, pyrenyl, benzofluoranthenyl, or chrysenyl group, or a substituted or unsubstituted thiophene, furan, pyrrole, imidazole, thiazole, oxazole, oxadiazole, triazole, bipyridyl, pyrimidyl, triazole, acridyl, pyridazine, pyrazinyl, phenoxazinyl, phthalazinyl, pyrido pyrimidinyl, pyrido pyrazinyl, pyrazino pyrazinyl, indole, carbazole, N-arylcarbazole, N-heteroaryl carbazole, N-alkyl carbazole, benzoxazole, benzimidazole, benzothiazole, benzocarbazole, benzothiophene, dibenzothiophenyl, thienothiophene, benzofuranyl, phenanthroline, thiazolyl, isoxazolyl, oxadiazolyl, thiadiazolyl, benzothiazolyl, phenothiazinyl, dibenzosilole, or dibenzofuranyl group,
R1 and R2 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms,
R1 and R2 are separate or combined with an adjacent group to form a ring, and
“a” and “b” are each independently an integer of 0 to 4.
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