| CPC B22F 1/102 (2022.01) [B22F 10/14 (2021.01); B22F 10/28 (2021.01); B22F 10/34 (2021.01); B33Y 40/10 (2020.01); B33Y 70/00 (2014.12); B33Y 70/10 (2020.01); C09D 7/20 (2018.01); C09D 7/62 (2018.01); C09D 7/65 (2018.01); C09D 7/70 (2018.01); C09D 175/04 (2013.01); B22F 10/322 (2021.01); B33Y 80/00 (2014.12)] | 20 Claims |

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1. A pulverant suitable to provide a three-dimensional low density foam by use of the pulverant in a layer-by-layer additive manufacturing process in which regions of respective layers of pulverant are selectively melted via introduction of electromagnetic energy, comprising:
a spray dried, crystalline and porous thermoplastic polyurethane polymer (TPU) coated base particle; wherein the base particle acts as a nucleation site;
wherein the base particle is an interstitial sacrificial particle, the sacrificial particle comprising at least one of a glass bead or a polymer bead having a gas therein to increase porosity in the TPU coating upon sacrifice of the sacrificial particle resulting in the low density of the low density foam;
wherein the spray dried, TPU coating comprises one or more first additives to facilitate generation of the nucleation site; and
wherein at least the nucleation site and the one or more first additives increase the crystallinity of the spray dried, TPU coating.
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