| CPC H01J 49/0004 (2013.01) [G01N 15/14 (2013.01); H01J 49/0463 (2013.01); H01J 49/164 (2013.01); G01N 2015/1006 (2013.01)] | 25 Claims |

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1. An apparatus comprising:
a. a sampler;
b. a laser ionisation system to receive a plume of material removed from a sample by the sampler, wherein the laser ionisation system comprises an ionisation system conduit comprising a tapered portion along which the internal diameter of the conduit is decreased, the tapered portion configured to lengthen the plume of material, the laser ionization system further comprising a pulsed laser adapted to ionise and generate elemental ions from the lengthened plume of material passing through or at the exit of the ionisation system conduit; and
c. a mass spectrometer to receive elemental ions from said ionisation system and to analyse said elemental ions.
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