US 12,276,605 B1
Detection and analysis method for rapid delineation of aging stages of styrene-butadiene-styrene modified asphalt
Derun Zhang, Hubei (CN); Peixin Xu, Hubei (CN); Ziyang Liu, Hubei (CN); Dongxing Luan, Hubei (CN); Zheng Liu, Hubei (CN); Yichen Guo, Hubei (CN); Pei Yu, Hubei (CN); Jinbiao Tang, Hubei (CN); Qisheng Hu, Hubei (CN); and Chenhui Peng, Hubei (CN)
Assigned to Huazhong University of Science and Technology, Wuhan (CN)
Filed by Huazhong University of Science and Technology, Hubei (CN)
Filed on Oct. 28, 2024, as Appl. No. 18/929,538.
Claims priority of application No. 202311415314.3 (CN), filed on Oct. 30, 2023.
Int. Cl. G01N 21/35 (2014.01); G01N 21/3563 (2014.01); G01N 21/3577 (2014.01)
CPC G01N 21/3563 (2013.01) [G01N 21/3577 (2013.01); G01N 2223/345 (2013.01)] 6 Claims
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1. A detection and analysis method for rapid delineation of aging stages of styrene-butadiene-styrene (SBS) modified asphalt, comprising the following steps:
(1) performing a Fourier transform infrared spectroscopy (FTIR) test on unaged SBS-modified asphalt samples, detecting the absorbance of infrared spectrum characteristic functional groups polystyrene and polybutadiene of unaged SBS-modified asphalt at 699 cm−1 and 966 cm−1, calculating a value of A699/A966, and recording the value as an unaged SBS copolymer index IB0/S0; and detecting the absorbance of the unaged SBS-modified asphalt at 1030 cm−1, 1456 cm−1, 1600 cm−1, and 1700 cm−1, calculating functional group indexes of sulfoxide group, aliphatic group, aromatic group and carbonyl of the unaged SBS-modified asphalt, and recording the same as indexes of unaged neat asphalt SI0=A1030/ΣA650˜2000, IB,aI0=A1456/ΣA650˜2000, ARI0=A1600/ΣA650˜2000, and CI0=A1700/ΣA650˜2000;
A699, A966, A1030, A1456, A1600, and A1700 referring to corresponding peak areas at infrared spectrum wave numbers of 699 cm−1, 966 cm−1, 1030 cm−1, 1456 cm−1, 1600 cm−1, and 1700 cm−1, and ΣA650˜2000 referring to a sum of peak areas at infrared spectrum wave numbers of 650 cm−1−2000 cm−1;
(2) performing the FTIR test on laboratory-fabricated SBS-modified asphalt samples or in-service SBS-modified asphalt pavement samples; detecting the absorbance of the laboratory-fabricated SBS-modified asphalt or in-service SBS-modified asphalt pavement samples at 699 cm−1 and 966 cm−1, calculating a value of A′699/A′966, and recording the value as an aging SBS copolymer index IB/S; and detecting the absorbance of the laboratory-fabricated SBS-modified asphalt or in-service SBS-modified asphalt pavement samples at 1030 cm−1, 1456 cm−1, 1600 cm−1, and 1700 cm−1, calculating functional group indexes of sulfoxide group, aliphatic group, aromatic group and carbonyl of the aged SBS-modified asphalt, and recording the same as indexes of aged neat asphalt SI=A′1030/ΣA′650˜2000, IB,aI=A′1456/ΣA′650˜2000, ARI=A′1600/ΣA′650˜2000, and CI=A′1700/ΣA′650˜2000; and
(3) delineating three aging stages of SBS-modified asphalt according to changes of infrared spectrum characteristic functional group indexes obtained by actual detection and calculation:
a, an SBS polymer swelling stage:

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b, an SBS polymer degradation stage:

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c, an asphalt component imbalance stage:

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