US 12,275,890 B2
Metal sulfide scale dissolver for oilfield application
Alex Yi-Tsung Lu, Houston, TX (US); and Zhiwei Yue, Houston, TX (US)
Assigned to Halliburton Energy Services, Inc., Houston, TX (US)
Filed by Halliburton Energy Services, Inc., Houston, TX (US)
Filed on Nov. 6, 2023, as Appl. No. 18/503,023.
Application 18/503,023 is a continuation in part of application No. 18/241,021, filed on Aug. 31, 2023.
Prior Publication US 2025/0075120 A1, Mar. 6, 2025
Int. Cl. E21B 37/06 (2006.01); C09K 8/532 (2006.01)
CPC C09K 8/532 (2013.01) [E21B 37/06 (2013.01)] 9 Claims
OG exemplary drawing
 
1. A method comprising:
providing a treatment fluid comprising:
a metal sulfide dissolver comprising a chelating agent, a boosting agent, a scaling agent, and a dispersing agent,
wherein the chelating agent comprises tetrakis (hydroxymethyl) phosphonium sulfate (THPS), salts thereof, or combinations thereof in an amount of about 0.03 wt % to about 0.1 wt % by weight of the treatment fluid;
wherein the boosting agent comprises citric acid in an amount of about 0.02 wt % to about 0.07 wt % by weight of the treatment fluid;
wherein the scaling agent comprises diethylene triamine penta (methylene phosphonic acid) (DTPMP) in an amount of about 0.003 wt % to about 0.02 wt % by weight of the treatment fluid;
wherein the dispersing agent comprises polydiallyldimethylammonium chloride (polyDADMAC) in an amount of about 25 ppm to about 200 ppm by weight of the treatment fluid; and
a base fluid;
contacting a metal sulfide scale with the treatment fluid; and
dissolving from 67% to 97% of the metal sulfide scale with the treatment fluid.