US 12,266,783 B2
Negative mass for lead-acid battery electrodes and lead-acid battery including same
Frank-Thomas Johns, Sarstedt (DE); Cornelia Brendel, Sarstedt (DE); Kavi Loganathan, Glendale, WI (US); and Matthew A. Spence, Lindenhurst, IL (US)
Assigned to Clarios Germany GmbH & Co. KG, Hannover (DE); and CPS Technology Holdings LLC, New York, NY (US)
Appl. No. 17/270,782
Filed by Clarios Germany GmbH & Co. KG, Hannover (DE); and CPS Technology Holdings LLC, New York, NY (US)
PCT Filed Aug. 30, 2019, PCT No. PCT/US2019/049166
§ 371(c)(1), (2) Date Feb. 23, 2021,
PCT Pub. No. WO2020/047478, PCT Pub. Date Mar. 5, 2020.
Claims priority of provisional application 62/725,329, filed on Aug. 31, 2018.
Prior Publication US 2021/0336249 A1, Oct. 28, 2021
Int. Cl. H01M 4/00 (2006.01); H01M 4/20 (2006.01); H01M 4/62 (2006.01); H01M 50/437 (2021.01); H01M 4/02 (2006.01); H01M 4/68 (2006.01); H01M 50/271 (2021.01); H01M 50/296 (2021.01)
CPC H01M 4/20 (2013.01) [H01M 4/627 (2013.01); H01M 50/437 (2021.01); H01M 2004/027 (2013.01); H01M 4/68 (2013.01); H01M 50/271 (2021.01); H01M 50/296 (2021.01)] 18 Claims
OG exemplary drawing
 
17. A lead-acid battery comprising:
a container with a cover, the container including one or more compartments;
one or more cell elements in the one or more compartments, the one or more cell elements comprising:
a positive electrode, the positive electrode having a positive current collector and a positive active material in contact with the positive current collector;
a negative electrode, the negative electrode having a current collector and negative paste in contact with the current collector, the negative paste comprising water, leady oxide, polymer fiber, sulfuric acid, and a blend comprising fine particle barium sulfate, with a particle size of 0.2 to 1.1 micrometers for mean D50, a first expander being a first oxylignin having a first molecular weight, is 0.1 wt % to 0.25 wt % with respect to a leady oxide weight a second expander being a second oxylignin having a second molecular weight is 0.1 wt % to 0.25 wt % with respect to a leady oxide weight, which is different from the first molecular weight, and a carbonaceous material; and
an absorbent glass mat separator between the positive electrode and the negative electrode;
electrolyte within the container; and
one or more terminal posts extending from the container or the cover and electrically coupled to the one or more cell elements.