| CPC H01L 21/823481 (2013.01) [H01L 21/0228 (2013.01); H01L 21/76224 (2013.01); H01L 27/0886 (2013.01)] | 20 Claims | 

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               1. A method comprising: 
            etching a trench in a substrate; 
                depositing an insulation material in the trench; 
                depositing a first ceramic dielectric material on the insulation material and in the trench with a first atomic layer deposition process, the first ceramic dielectric material having a first carbon concentration; 
                depositing a second ceramic dielectric material on the first ceramic dielectric material and in the trench with a second atomic layer deposition process, the second ceramic dielectric material having a second carbon concentration, the second carbon concentration being greater than the first carbon concentration; 
                planarizing a top surface of the insulation material with a top surface of the first ceramic dielectric material and a top surface of the second ceramic dielectric material; and 
                recessing the top surface of the insulation material from the top surface of the first ceramic dielectric material and the top surface of the second ceramic dielectric material. 
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