| CPC B32B 7/027 (2019.01) [B32B 5/024 (2013.01); B32B 9/02 (2013.01); B32B 17/02 (2013.01); B32B 33/00 (2013.01); C04B 35/04 (2013.01); C04B 35/10 (2013.01); C04B 35/453 (2013.01); C04B 38/0058 (2013.01); C04B 38/0064 (2013.01); C04B 38/0096 (2013.01); C08J 5/121 (2013.01); C09D 1/00 (2013.01); C09D 5/08 (2013.01); C09D 201/00 (2013.01); C23C 8/02 (2013.01); C23C 8/52 (2013.01); C23C 22/06 (2013.01); D06M 11/44 (2013.01); D06M 11/83 (2013.01); D06M 23/06 (2013.01); F28F 19/06 (2013.01); B32B 2255/20 (2013.01); B32B 2262/08 (2013.01); B32B 2262/101 (2013.01); B32B 2262/128 (2021.05); B32B 2305/188 (2013.01); B32B 2307/304 (2013.01); B32B 2307/728 (2013.01); B32B 2307/73 (2013.01); B32B 2315/02 (2013.01); B32B 2315/08 (2013.01); B32B 2317/10 (2013.01); C04B 2235/3206 (2013.01); C04B 2235/3217 (2013.01); C04B 2235/3284 (2013.01); C04B 2235/96 (2013.01); D06M 2101/06 (2013.01); D06M 2101/32 (2013.01); D06M 2101/34 (2013.01); D06M 2200/12 (2013.01)] | 20 Claims |

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1. An assembly of materials comprising a top surface and a bottom surface, comprising:
(a) x At layers of breathable material, wherein the At layers comprise a topmost layer that comprises the top surface;
(b) y Ab layers of breathable material, wherein the Ab layers comprise a bottommost layer that comprises the bottom surface; and
(c) z B layers of breathable insulating or structural material between x At layers and y Ab layers,
wherein x, y, and z are the same or different number of layers,
wherein the At layers and the Ab layers each comprise a binderless ceramic material on a substrate,
wherein the binderless ceramic material on at least one At layer and/or at least one Ab layer is a partially filled porous structure,
wherein pores of the binderless ceramic material are partially filled with a second ceramic material or with a molecule with a head group and a tail group, and
wherein the binderless ceramic material on each At layer and/or each Ab layer is the same or different.
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