US 12,263,622 B1
Process for producing isocyanate-based foam construction boards
John B. Letts, Carmel, IN (US); and Chunhua Yao, Carmel, IN (US)
Assigned to Holcim Technology Ltd, Zug (CH)
Filed by Holcim Technology Ltd, Zug (CH)
Filed on Jan. 4, 2022, as Appl. No. 17/568,265.
Claims priority of provisional application 63/133,557, filed on Jan. 4, 2021.
Int. Cl. C08G 18/40 (2006.01); B29C 44/14 (2006.01); C08G 18/42 (2006.01); C08G 18/48 (2006.01); C08G 18/76 (2006.01); C08G 65/26 (2006.01); C08J 9/12 (2006.01); C08J 9/14 (2006.01); C08K 5/00 (2006.01); E04B 1/80 (2006.01); B29K 75/00 (2006.01); B29L 7/00 (2006.01); B29L 9/00 (2006.01)
CPC B29C 44/14 (2013.01) [C08G 18/4208 (2013.01); C08J 9/141 (2013.01); C08K 5/0008 (2013.01); E04B 1/80 (2013.01); B29K 2075/00 (2013.01); B29L 2007/002 (2013.01); B29L 2009/00 (2013.01); C08J 2203/14 (2013.01); C08J 2375/06 (2013.01)] 14 Claims
 
1. A process for producing a polyurethane or polyisocyanurate foam construction board, the process comprising:
(i) providing an A-side reactant stream that includes an isocyanate containing compound;
(ii) providing a B-side reactant stream that includes an aromatic polyester polyol, a fluorinated additive, at least one surfactant, and a physical blowing agent mixture, where said physical blowing agent mixture includes an acyclic pentane and a blowing agent additive selected from the group consisting of ketones, aldehydes, ethers, esters, chlorinated hydrocarbons, and aromatics, where the blowing agent additive has a Hansen Solubility Parameter (δt) that is greater than 17 MPa−0.5, where the fluorinated additive is provided in an amount of from about 2 to about 24 wt % based upon the entire weight of the physical blowing agent mixture, where the fluorinated additive is emulsified in the at least one surfactant prior to forming the B-side reactant stream, where the B-side reactant stream is devoid of filler; and
(iii) mixing the A-side reactant stream with the B-side reactant stream to produce a reaction mixture.