US 12,263,470 B2
Method of improving selective hydrogenation of unsaturated hydrocarbon in aromatic fraction through catalyst pretreatment
Sang Il Lee, Daejeon (KR); and Ji Hoon Lee, Daejeon (KR)
Assigned to SK Innovation Co., Ltd., Seoul (KR); and SK Geo Centric Co., Ltd., Seoul (KR)
Filed by SK Innovation Co., Ltd., Seoul (KR); and SK Geo Centric Co., Ltd., Seoul (KR)
Filed on May 21, 2024, as Appl. No. 18/669,691.
Application 18/669,691 is a division of application No. 17/973,669, filed on Oct. 26, 2022, granted, now 12,011,709.
Claims priority of application No. 10-2021-0144230 (KR), filed on Oct. 27, 2021.
Prior Publication US 2024/0299912 A1, Sep. 12, 2024
Int. Cl. B01J 21/04 (2006.01); B01J 23/755 (2006.01); B01J 23/882 (2006.01); B01J 23/883 (2006.01); B01J 35/30 (2024.01); B01J 37/14 (2006.01); B01J 37/18 (2006.01); B01J 37/20 (2006.01); C07C 5/11 (2006.01); C07C 5/27 (2006.01); C07C 6/06 (2006.01)
CPC B01J 23/883 (2013.01) [B01J 21/04 (2013.01); B01J 23/755 (2013.01); B01J 23/882 (2013.01); B01J 35/394 (2024.01); B01J 37/14 (2013.01); B01J 37/18 (2013.01); B01J 37/20 (2013.01); C07C 5/11 (2013.01); C07C 5/2735 (2013.01); C07C 5/2754 (2013.01); C07C 6/06 (2013.01); C07C 2521/04 (2013.01); C07C 2523/755 (2013.01); C07C 2523/882 (2013.01); C07C 2523/883 (2013.01)] 20 Claims
 
1. A method for removing unsaturated hydrocarbons from aromatic hydrocarbons, which comprises the steps of:
providing an aromatic hydrocarbon-containing feedstock having a bromine index of at least 30; and
forming an aromatic hydrocarbon-containing product having a decreased bromine index compared to the feedstock by hydrogenating the aromatic hydrocarbon-containing feedstock in presence of a selective hydrogenation catalyst prepared using a method comprising the steps of:
a) providing a calcined catalyst containing nickel and molybdenum;
b) sulfiding the calcined catalyst containing nickel and molybdenum to give a sulfided catalyst containing nickel and molybdenum;
c) carrying out an oxidation treatment of the sulfided catalyst containing nickel and molybdenum at a temperature exceeding 250° C. to give an oxidized catalyst containing nickel and molybdenum; and
d) carrying out a reduction treatment of the oxidized catalyst containing nickel and molybdenum to give a reduced catalyst containing nickel and molybdenum.